Assembly and stepwise oxidation of interpenetrated coordination cages based on phenothiazine

Marina Frank, Jakob Hey, Ilker Balcioglu, Yu Sheng Chen, Dietmar Stalke, Tomoyoshi Suenobu, Shunichi Fukuzumi, Holm Frauendorf, Guido H. Clever

Research output: Contribution to journalArticlepeer-review

95 Scopus citations

Abstract

A breath of fresh air is sufficient for the eightfold S-monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square-planar-coordinated PdII cations. Besides these two cages, which were both characterized by X-ray crystallography, an eightfold S-dioxygenated double-cage was obtained under harsher oxidation conditions.

Original languageEnglish
Pages (from-to)10102-10106
Number of pages5
JournalAngewandte Chemie - International Edition
Volume52
Issue number38
DOIs
StatePublished - 16 Sep 2013

Keywords

  • cage compounds
  • interpenetration
  • phenothiazines
  • redox chemistry
  • supramolecular chemistry

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