Assembly and stepwise oxidation of interpenetrated coordination cages based on phenothiazine

Marina Frank; Jakob Hey; Ilker Balcioglu; Yu Sheng Chen; Dietmar Stalke; Tomoyoshi Suenobu; Shunichi Fukuzumi; Holm Frauendorf; Guido H. Clever

doi:10.1002/anie.201302536

Assembly and stepwise oxidation of interpenetrated coordination cages based on phenothiazine

Marina Frank, Jakob Hey, Ilker Balcioglu, Yu Sheng Chen, Dietmar Stalke, Tomoyoshi Suenobu, Shunichi Fukuzumi, Holm Frauendorf, Guido H. Clever

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

96 Scopus citations

Abstract

A breath of fresh air is sufficient for the eightfold S-monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square-planar-coordinated Pd^II cations. Besides these two cages, which were both characterized by X-ray crystallography, an eightfold S-dioxygenated double-cage was obtained under harsher oxidation conditions.

Original language	English
Pages (from-to)	10102-10106
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	38
DOIs	https://doi.org/10.1002/anie.201302536
State	Published - 16 Sep 2013

Keywords

cage compounds
interpenetration
phenothiazines
redox chemistry
supramolecular chemistry

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abstract = "A breath of fresh air is sufficient for the eightfold S-monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square-planar-coordinated PdII cations. Besides these two cages, which were both characterized by X-ray crystallography, an eightfold S-dioxygenated double-cage was obtained under harsher oxidation conditions.",

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T1 - Assembly and stepwise oxidation of interpenetrated coordination cages based on phenothiazine

AU - Frank, Marina

AU - Hey, Jakob

AU - Balcioglu, Ilker

AU - Chen, Yu Sheng

AU - Stalke, Dietmar

AU - Suenobu, Tomoyoshi

AU - Fukuzumi, Shunichi

AU - Frauendorf, Holm

AU - Clever, Guido H.

PY - 2013/9/16

Y1 - 2013/9/16

N2 - A breath of fresh air is sufficient for the eightfold S-monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square-planar-coordinated PdII cations. Besides these two cages, which were both characterized by X-ray crystallography, an eightfold S-dioxygenated double-cage was obtained under harsher oxidation conditions.

AB - A breath of fresh air is sufficient for the eightfold S-monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square-planar-coordinated PdII cations. Besides these two cages, which were both characterized by X-ray crystallography, an eightfold S-dioxygenated double-cage was obtained under harsher oxidation conditions.

KW - cage compounds

KW - interpenetration

KW - phenothiazines

KW - redox chemistry

KW - supramolecular chemistry

UR - http://www.scopus.com/inward/record.url?scp=84884264920&partnerID=8YFLogxK

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 38

ER -

Assembly and stepwise oxidation of interpenetrated coordination cages based on phenothiazine

Abstract

Keywords

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