Aqueous hydrogenation of carbon dioxide catalysed by water-soluble ruthenium aqua complexes under acidic conditions

Hideki Hayashi; Seiji Ogo; Shunichi Fukuzumi

doi:10.1039/b411633j

Aqueous hydrogenation of carbon dioxide catalysed by water-soluble ruthenium aqua complexes under acidic conditions

Hideki Hayashi, Seiji Ogo, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

134 Scopus citations

Abstract

Hydrogenation of carbon dioxide (P(H₂/CO₂) = 5.5/2.5 MPa) into formic acid (HCOOH) under acidic conditions (pH 2.5-5.0) in water has been achieved by using water-soluble ruthenium aqua catalysts [η⁶-C₆Me₆)Ru^II(L)(OH ₂)]SO₄ (L = 2,2′-bipyridine or 4,4′-dimethoxy- 2, 2′-bipyridine).

Original language	English
Pages (from-to)	2714-2715
Number of pages	2
Journal	Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/b411633j
State	Published - 7 Dec 2004

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abstract = "Hydrogenation of carbon dioxide (P(H2/CO2) = 5.5/2.5 MPa) into formic acid (HCOOH) under acidic conditions (pH 2.5-5.0) in water has been achieved by using water-soluble ruthenium aqua catalysts [η6-C6Me6)RuII(L)(OH 2)]SO4 (L = 2,2′-bipyridine or 4,4′-dimethoxy- 2, 2′-bipyridine).",

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AU - Hayashi, Hideki

AU - Ogo, Seiji

AU - Fukuzumi, Shunichi

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Y1 - 2004/12/7

N2 - Hydrogenation of carbon dioxide (P(H2/CO2) = 5.5/2.5 MPa) into formic acid (HCOOH) under acidic conditions (pH 2.5-5.0) in water has been achieved by using water-soluble ruthenium aqua catalysts [η6-C6Me6)RuII(L)(OH 2)]SO4 (L = 2,2′-bipyridine or 4,4′-dimethoxy- 2, 2′-bipyridine).

AB - Hydrogenation of carbon dioxide (P(H2/CO2) = 5.5/2.5 MPa) into formic acid (HCOOH) under acidic conditions (pH 2.5-5.0) in water has been achieved by using water-soluble ruthenium aqua catalysts [η6-C6Me6)RuII(L)(OH 2)]SO4 (L = 2,2′-bipyridine or 4,4′-dimethoxy- 2, 2′-bipyridine).

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DO - 10.1039/b411633j

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JO - Chemical Communications

JF - Chemical Communications

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Aqueous hydrogenation of carbon dioxide catalysed by water-soluble ruthenium aqua complexes under acidic conditions

Abstract

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