Abstract
For the recognition and sensing of anionic analytes, comparative studies were carried out on the anion bindings of pyrophosphate, H2PO 4-, and dicarboxylates to the anthracene derivatives bearing two urea groups on the 1,8 and 9,10-positions as fluorescent chemosensors for anions. Their binding properties were compared using fluorescence and 1H NMR, and the results were rationalized with an ab initio study.
| Original language | English |
|---|---|
| Pages (from-to) | 4545-4550 |
| Number of pages | 6 |
| Journal | Tetrahedron |
| Volume | 61 |
| Issue number | 19 |
| DOIs | |
| State | Published - 9 May 2005 |
Bibliographical note
Funding Information:This work was supported by Koreans Science and Engineering Foundation (R14-2003-014-01001-0), the Creative Research Initiative of the Korean Ministry of Science and Technology, and BK21. K. M. K. S. is thankful for a Brain Pool Fellowship.
Keywords
- Adipate
- Anion
- Anion-receptor
- Dicarboxylates
- Fluorescence
- Fluorescence chemosensor
- Molecular recognition
- Pyrophosphate
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