Anionic living polymerization of monomers with photo-electronic properties for control of polymeric nano architectures

Yeong Deuk Shin; Young Sun Cho; Jang Joo Kim; Jae Suk Lee; Song Hee Han; Jeong Weon Wu

doi:10.1080/10587250008024853

Anionic living polymerization of monomers with photo-electronic properties for control of polymeric nano architectures

Yeong Deuk Shin, Young Sun Cho, Jang Joo Kim, Jae Suk Lee, Song Hee Han, Jeong Weon Wu

Department of Physics

Research output: Contribution to journal › Conference article › peer-review

6 Scopus citations

Abstract

Block copolymers, 9-ethylcarbazolyl methacrylate (CzMA) with 3-nitro-9-ethylcarbazolyl methacrylate (NCzMA), and styrene with optically functionalized isocyanates containing disperse red 1 (DR1NCO) and (s)-(-)-2-methylbutanol (MBI), were prepared by anionic polymerization for photo-electronic materials. The living condition of CzMA was found at -78°C for 3 h with diethyl zinc and block copolymers of CzMA with NCzMA were synthesized successfully. The polymers show potential to be used as energy transfer materials in UV and PL spectra. Block copolymers of styrene with optically functionalized isocyanates were also synthesized with high yield and the polymers showed the large optical activity at 476 nm.

Original language	English
Pages (from-to)	9-14
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	349
DOIs	https://doi.org/10.1080/10587250008024853
State	Published - 2000
Event	Proceedings of the Korea-Japan Joint Forum 1999 Organic Materials for Electronics and Photonics - Kyongju, South Korea Duration: 9 Sep 1999 → 11 Sep 1999

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10.1080/10587250008024853

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@article{23501ddb8e1b4b6b80fa1512dc5b3070,

title = "Anionic living polymerization of monomers with photo-electronic properties for control of polymeric nano architectures",

abstract = "Block copolymers, 9-ethylcarbazolyl methacrylate (CzMA) with 3-nitro-9-ethylcarbazolyl methacrylate (NCzMA), and styrene with optically functionalized isocyanates containing disperse red 1 (DR1NCO) and (s)-(-)-2-methylbutanol (MBI), were prepared by anionic polymerization for photo-electronic materials. The living condition of CzMA was found at -78°C for 3 h with diethyl zinc and block copolymers of CzMA with NCzMA were synthesized successfully. The polymers show potential to be used as energy transfer materials in UV and PL spectra. Block copolymers of styrene with optically functionalized isocyanates were also synthesized with high yield and the polymers showed the large optical activity at 476 nm.",

author = "Shin, {Yeong Deuk} and Cho, {Young Sun} and Kim, {Jang Joo} and Lee, {Jae Suk} and Han, {Song Hee} and Wu, {Jeong Weon}",

year = "2000",

doi = "10.1080/10587250008024853",

language = "English",

volume = "349",

pages = "9--14",

journal = "Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals",

issn = "1058-725X",

publisher = "Taylor and Francis Ltd.",

note = "Proceedings of the Korea-Japan Joint Forum 1999 Organic Materials for Electronics and Photonics ; Conference date: 09-09-1999 Through 11-09-1999",

}

Anionic living polymerization of monomers with photo-electronic properties for control of polymeric nano architectures. / Shin, Yeong Deuk; Cho, Young Sun; Kim, Jang Joo et al.
In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 349, 2000, p. 9-14.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - Anionic living polymerization of monomers with photo-electronic properties for control of polymeric nano architectures

AU - Shin, Yeong Deuk

AU - Cho, Young Sun

AU - Kim, Jang Joo

AU - Lee, Jae Suk

AU - Han, Song Hee

AU - Wu, Jeong Weon

PY - 2000

Y1 - 2000

N2 - Block copolymers, 9-ethylcarbazolyl methacrylate (CzMA) with 3-nitro-9-ethylcarbazolyl methacrylate (NCzMA), and styrene with optically functionalized isocyanates containing disperse red 1 (DR1NCO) and (s)-(-)-2-methylbutanol (MBI), were prepared by anionic polymerization for photo-electronic materials. The living condition of CzMA was found at -78°C for 3 h with diethyl zinc and block copolymers of CzMA with NCzMA were synthesized successfully. The polymers show potential to be used as energy transfer materials in UV and PL spectra. Block copolymers of styrene with optically functionalized isocyanates were also synthesized with high yield and the polymers showed the large optical activity at 476 nm.

AB - Block copolymers, 9-ethylcarbazolyl methacrylate (CzMA) with 3-nitro-9-ethylcarbazolyl methacrylate (NCzMA), and styrene with optically functionalized isocyanates containing disperse red 1 (DR1NCO) and (s)-(-)-2-methylbutanol (MBI), were prepared by anionic polymerization for photo-electronic materials. The living condition of CzMA was found at -78°C for 3 h with diethyl zinc and block copolymers of CzMA with NCzMA were synthesized successfully. The polymers show potential to be used as energy transfer materials in UV and PL spectra. Block copolymers of styrene with optically functionalized isocyanates were also synthesized with high yield and the polymers showed the large optical activity at 476 nm.

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U2 - 10.1080/10587250008024853

DO - 10.1080/10587250008024853

M3 - Conference article

AN - SCOPUS:0034480125

SN - 1058-725X

VL - 349

SP - 9

EP - 14

JO - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

T2 - Proceedings of the Korea-Japan Joint Forum 1999 Organic Materials for Electronics and Photonics

Y2 - 9 September 1999 through 11 September 1999

ER -

Anionic living polymerization of monomers with photo-electronic properties for control of polymeric nano architectures

Abstract

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