Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa): Novel heterogeneous catalytic activities

Young Min Lee; Sung Jin Hong; Hee Jin Kim; Sun Hwa Lee; Han Kwak; Cheal Kim; Sung Jin Kim; Youngmee Kim

doi:10.1016/j.inoche.2006.11.001

Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa): Novel heterogeneous catalytic activities

Young Min Lee, Sung Jin Hong, Hee Jin Kim, Sun Hwa Lee, Han Kwak, Cheal Kim, Sung Jin Kim, Youngmee Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

The reaction of ZnSO₄ with 2,2′-dipyridylamine (Hdpa) results in a coordination polymer 1 while other zinc(II) salts (bromide 2 or benzoateanions 3) produce usually monomers which can generate hydrogen-bonded polymers. The coordination polymer 1 and hydrogen-bonded polymer 2 have shown, surprisingly, unusual heterogeneous catalytic activities on transesterification reaction of esters, but the monomeric compound 3 catalyzed the reaction homogeneously.

Original language	English
Pages (from-to)	287-291
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	3
DOIs	https://doi.org/10.1016/j.inoche.2006.11.001
State	Published - Mar 2007

Bibliographical note

Funding Information:
Financial support from the Korea Research Foundation (2002-070-C00053), The Seoul R&BD Program, The Korean Science and Engineering Foundation (R01-2005-000-10490-0(2005)), and the SRC program of MOST/KOSEF through the Center for Intelligent Nano-Bio Materials at Ewha Womans University (R11-2005-008-00000-0) is gratefully acknowledged.

Keywords

2,2′-Dipyridylamine ligand
Heterogeneous catalyst
Transesterification
Znic(II) coordination polymer

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title = "Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa): Novel heterogeneous catalytic activities",

abstract = "The reaction of ZnSO4 with 2,2′-dipyridylamine (Hdpa) results in a coordination polymer 1 while other zinc(II) salts (bromide 2 or benzoateanions 3) produce usually monomers which can generate hydrogen-bonded polymers. The coordination polymer 1 and hydrogen-bonded polymer 2 have shown, surprisingly, unusual heterogeneous catalytic activities on transesterification reaction of esters, but the monomeric compound 3 catalyzed the reaction homogeneously.",

keywords = "2,2′-Dipyridylamine ligand, Heterogeneous catalyst, Transesterification, Znic(II) coordination polymer",

author = "Lee, {Young Min} and Hong, {Sung Jin} and Kim, {Hee Jin} and Lee, {Sun Hwa} and Han Kwak and Cheal Kim and Kim, {Sung Jin} and Youngmee Kim",

note = "Funding Information: Financial support from the Korea Research Foundation (2002-070-C00053), The Seoul R&BD Program, The Korean Science and Engineering Foundation (R01-2005-000-10490-0(2005)), and the SRC program of MOST/KOSEF through the Center for Intelligent Nano-Bio Materials at Ewha Womans University (R11-2005-008-00000-0) is gratefully acknowledged. ",

year = "2007",

month = mar,

doi = "10.1016/j.inoche.2006.11.001",

language = "English",

volume = "10",

pages = "287--291",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

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T2 - Novel heterogeneous catalytic activities

AU - Lee, Young Min

AU - Hong, Sung Jin

AU - Kim, Hee Jin

AU - Lee, Sun Hwa

AU - Kwak, Han

AU - Kim, Cheal

AU - Kim, Sung Jin

AU - Kim, Youngmee

N1 - Funding Information: Financial support from the Korea Research Foundation (2002-070-C00053), The Seoul R&BD Program, The Korean Science and Engineering Foundation (R01-2005-000-10490-0(2005)), and the SRC program of MOST/KOSEF through the Center for Intelligent Nano-Bio Materials at Ewha Womans University (R11-2005-008-00000-0) is gratefully acknowledged.

PY - 2007/3

Y1 - 2007/3

N2 - The reaction of ZnSO4 with 2,2′-dipyridylamine (Hdpa) results in a coordination polymer 1 while other zinc(II) salts (bromide 2 or benzoateanions 3) produce usually monomers which can generate hydrogen-bonded polymers. The coordination polymer 1 and hydrogen-bonded polymer 2 have shown, surprisingly, unusual heterogeneous catalytic activities on transesterification reaction of esters, but the monomeric compound 3 catalyzed the reaction homogeneously.

AB - The reaction of ZnSO4 with 2,2′-dipyridylamine (Hdpa) results in a coordination polymer 1 while other zinc(II) salts (bromide 2 or benzoateanions 3) produce usually monomers which can generate hydrogen-bonded polymers. The coordination polymer 1 and hydrogen-bonded polymer 2 have shown, surprisingly, unusual heterogeneous catalytic activities on transesterification reaction of esters, but the monomeric compound 3 catalyzed the reaction homogeneously.

KW - 2,2′-Dipyridylamine ligand

KW - Heterogeneous catalyst

KW - Transesterification

KW - Znic(II) coordination polymer

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U2 - 10.1016/j.inoche.2006.11.001

DO - 10.1016/j.inoche.2006.11.001

M3 - Article

AN - SCOPUS:33846922603

SN - 1387-7003

VL - 10

SP - 287

EP - 291

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 3

ER -

Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa): Novel heterogeneous catalytic activities

Abstract

Bibliographical note

Keywords

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