An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion

Atsutoshi Yokoyama, Jung Eun Han, Kenneth D. Karlin, Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

20 Scopus citations

Abstract

Reaction of a nonheme iron(III)-peroxo complex, [FeIII(14-TMC)(O2)]+, with NO+, a transformation which is essentially isoelectronic with that for nitric oxide dioxygenases [Fe(III)(O2 = ) + NO], affords an iron(IV)-oxo complex, [FeIV(14-TMC)(O)]2+, and nitrogen dioxide (NO2), followed by conversion to an iron(III)-nitrato complex, [FeIII(14-TMC)(NO3)(F)]+. 2014

Original languageEnglish
Pages (from-to)1742-1744
Number of pages3
JournalChemical Communications
Volume50
Issue number14
DOIs
StatePublished - 21 Jan 2014

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