An Alkylperoxoiron(III) Intermediate and Its Role in the Oxidation of Aliphatic CH Bonds

Jinheung Kim; Edmund Larka; Elizabeth C. Wilkinson; Lawrence Que

doi:10.1002/anie.199520481

An Alkylperoxoiron(III) Intermediate and Its Role in the Oxidation of Aliphatic CH Bonds

Jinheung Kim, Edmund Larka, Elizabeth C. Wilkinson, Lawrence Que

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

98 Scopus citations

Abstract

Based on EPR, Raman, and mass spectral evidence, the formula 1 best describes the transient intermediate which forms upon treatment of 2 with tert‐butyl hydroperoxide in the presence of alcohol. Kinetic evidence suggests that its decomposition by oxidation of the bound alcohol proceeds via the transition state 3. tpa = tris(2‐pyridylmethyl)amine. (Formula Presented.) (Figure Presented.)

Original language	English
Pages (from-to)	2048-2051
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	34
Issue number	18
DOIs	https://doi.org/10.1002/anie.199520481
State	Published - 2 Oct 1995

Keywords

CH activation
iron compounds
mass spectrometry
peroxo complexes

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title = "An Alkylperoxoiron(III) Intermediate and Its Role in the Oxidation of Aliphatic CH Bonds",

abstract = "Based on EPR, Raman, and mass spectral evidence, the formula 1 best describes the transient intermediate which forms upon treatment of 2 with tert‐butyl hydroperoxide in the presence of alcohol. Kinetic evidence suggests that its decomposition by oxidation of the bound alcohol proceeds via the transition state 3. tpa = tris(2‐pyridylmethyl)amine. (Formula Presented.) (Figure Presented.)",

keywords = "CH activation, iron compounds, mass spectrometry, peroxo complexes",

author = "Jinheung Kim and Edmund Larka and Wilkinson, \{Elizabeth C.\} and Lawrence Que",

year = "1995",

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journal = "Angewandte Chemie - International Edition",

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T1 - An Alkylperoxoiron(III) Intermediate and Its Role in the Oxidation of Aliphatic CH Bonds

AU - Kim, Jinheung

AU - Larka, Edmund

AU - Wilkinson, Elizabeth C.

AU - Que, Lawrence

PY - 1995/10/2

Y1 - 1995/10/2

N2 - Based on EPR, Raman, and mass spectral evidence, the formula 1 best describes the transient intermediate which forms upon treatment of 2 with tert‐butyl hydroperoxide in the presence of alcohol. Kinetic evidence suggests that its decomposition by oxidation of the bound alcohol proceeds via the transition state 3. tpa = tris(2‐pyridylmethyl)amine. (Formula Presented.) (Figure Presented.)

AB - Based on EPR, Raman, and mass spectral evidence, the formula 1 best describes the transient intermediate which forms upon treatment of 2 with tert‐butyl hydroperoxide in the presence of alcohol. Kinetic evidence suggests that its decomposition by oxidation of the bound alcohol proceeds via the transition state 3. tpa = tris(2‐pyridylmethyl)amine. (Formula Presented.) (Figure Presented.)

KW - CH activation

KW - iron compounds

KW - mass spectrometry

KW - peroxo complexes

UR - https://www.scopus.com/pages/publications/33748487841

U2 - 10.1002/anie.199520481

DO - 10.1002/anie.199520481

M3 - Article

AN - SCOPUS:33748487841

SN - 0570-0833

VL - 34

SP - 2048

EP - 2051

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 18

ER -

An Alkylperoxoiron(III) Intermediate and Its Role in the Oxidation of Aliphatic CH Bonds

Abstract

Keywords

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