Abstract
Based on EPR, Raman, and mass spectral evidence, the formula 1 best describes the transient intermediate which forms upon treatment of 2 with tert‐butyl hydroperoxide in the presence of alcohol. Kinetic evidence suggests that its decomposition by oxidation of the bound alcohol proceeds via the transition state 3. tpa = tris(2‐pyridylmethyl)amine. (Formula Presented.) (Figure Presented.)
Original language | English |
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Pages (from-to) | 2048-2051 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 34 |
Issue number | 18 |
DOIs | |
State | Published - 2 Oct 1995 |
Keywords
- CH activation
- iron compounds
- mass spectrometry
- peroxo complexes