Alkyne oxidation by nonheme iron catalysts and hydroperoxides

Ju Yeon Ryu; Soonyoung Heo; Philsung Park; Wonwoo Nam; Jinheung Kim

doi:10.1016/j.inoche.2004.02.010

Alkyne oxidation by nonheme iron catalysts and hydroperoxides

Ju Yeon Ryu, Soonyoung Heo, Philsung Park, Wonwoo Nam, Jinheung Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Alkynes were oxidized by hydrogen peroxide and tert-butyl hydroperoxide catalyzed by nonheme iron complexes under aerobic and anaerobic conditions: the formation of diketone and α,β-acetylenic oxidation products was significantly affected by the oxidants, and product yields were markedly influenced by the presence of O₂.

Original language	English
Pages (from-to)	534-537
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	7
Issue number	4
DOIs	https://doi.org/10.1016/j.inoche.2004.02.010
State	Published - Apr 2004

Bibliographical note

Funding Information:
We thank the Korea Research Foundation (Grant No. DP0270 to W.N.) for financial support.

Keywords

Alkyne oxidation
Hydroperoxide
Nonheme iron complex
Oxygen activation

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10.1016/j.inoche.2004.02.010

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title = "Alkyne oxidation by nonheme iron catalysts and hydroperoxides",

abstract = "Alkynes were oxidized by hydrogen peroxide and tert-butyl hydroperoxide catalyzed by nonheme iron complexes under aerobic and anaerobic conditions: the formation of diketone and α,β-acetylenic oxidation products was significantly affected by the oxidants, and product yields were markedly influenced by the presence of O2.",

keywords = "Alkyne oxidation, Hydroperoxide, Nonheme iron complex, Oxygen activation",

author = "Ryu, \{Ju Yeon\} and Soonyoung Heo and Philsung Park and Wonwoo Nam and Jinheung Kim",

note = "Funding Information: We thank the Korea Research Foundation (Grant No. DP0270 to W.N.) for financial support. ",

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language = "English",

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T1 - Alkyne oxidation by nonheme iron catalysts and hydroperoxides

AU - Ryu, Ju Yeon

AU - Heo, Soonyoung

AU - Park, Philsung

AU - Nam, Wonwoo

AU - Kim, Jinheung

N1 - Funding Information: We thank the Korea Research Foundation (Grant No. DP0270 to W.N.) for financial support.

PY - 2004/4

Y1 - 2004/4

N2 - Alkynes were oxidized by hydrogen peroxide and tert-butyl hydroperoxide catalyzed by nonheme iron complexes under aerobic and anaerobic conditions: the formation of diketone and α,β-acetylenic oxidation products was significantly affected by the oxidants, and product yields were markedly influenced by the presence of O2.

AB - Alkynes were oxidized by hydrogen peroxide and tert-butyl hydroperoxide catalyzed by nonheme iron complexes under aerobic and anaerobic conditions: the formation of diketone and α,β-acetylenic oxidation products was significantly affected by the oxidants, and product yields were markedly influenced by the presence of O2.

KW - Alkyne oxidation

KW - Hydroperoxide

KW - Nonheme iron complex

KW - Oxygen activation

UR - https://www.scopus.com/pages/publications/1642375677

U2 - 10.1016/j.inoche.2004.02.010

DO - 10.1016/j.inoche.2004.02.010

M3 - Article

AN - SCOPUS:1642375677

SN - 1387-7003

VL - 7

SP - 534

EP - 537

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 4

ER -

Alkyne oxidation by nonheme iron catalysts and hydroperoxides

Abstract

Bibliographical note

Keywords

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