Adsorption of Ba²⁺ and Sr²⁺ on Ti₃C₂T_x MXene in model fracking wastewater

Wastewater from hydraulic fracking contains both organic and inorganic pollutants; the latter include radioactive nuclides such as Ba²⁺ and Sr²⁺. We explored whether MXene (Ti₃C₂T_x), a novel adsorbent, could remove Ba²⁺ and Sr²⁺ from model wastewater. Zeta potential analysis showed that MXene had a high negative surface charge. MXene adsorbed Ba²⁺ and Sr²⁺ via electrostatic attraction, as confirmed by the adsorption at different solution pH values and in the presence of various concentrations of other ions (NaCl and CaCl₂). MXene exhibited outstanding adsorption of Ba²⁺ and Sr²⁺, to approximately 180 and 225 mg g⁻¹, respectively, when 1 g L⁻¹ MXene was admixed with adsorbates at 2 g L⁻¹. MXene exhibited very rapid adsorption kinetics, attaining equilibrium within 1 h. X-ray photoelectron spectroscopy and Fourier-transform infrared spectroscopy revealed that MXene adsorbed Ba²⁺ and Sr²⁺, respectively, via ion exchange and inner-sphere complex formation. Finally, we performed MXene reusability tests; reusability was excellent over at least four cycles. Thus, MXene removed Ba²⁺ and Sr²⁺ from model fracking wastewater.