Addition Reaction of Allylic Stannanes to the Triplet Excited State of C60 via Photoinduced Electron Transfer Process Leading to Asymmetric Hybridization Chemistry for Fullerene Terpenoid

Koichi Mikami; Shoji Matsumoto; Takayuki Tonoi; Tomoyoshi Suenobu; Akito Ishida; Shunichi Fukuzumi

doi:10.1055/s-1997-720

Addition Reaction of Allylic Stannanes to the Triplet Excited State of C₆₀ via Photoinduced Electron Transfer Process Leading to Asymmetric Hybridization Chemistry for Fullerene Terpenoid

Koichi Mikami, Shoji Matsumoto, Takayuki Tonoi, Tomoyoshi Suenobu, Akito Ishida, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Addition of allylic stannanes to C₆₀ takes place under UV-irradiation in benzene as well as benzonitrile to yield the allylic fullerenes, of which the asymmetric version with pinene-derived chiral allylic stannane leads to an enantio-pure fullerene terpenoid.

Original language	English
Pages (from-to)	85-87
Number of pages	3
Journal	Synlett
Volume	1997
Issue number	1
DOIs	https://doi.org/10.1055/s-1997-720
State	Published - 1997

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title = "Addition Reaction of Allylic Stannanes to the Triplet Excited State of C60 via Photoinduced Electron Transfer Process Leading to Asymmetric Hybridization Chemistry for Fullerene Terpenoid",

abstract = "Addition of allylic stannanes to C60 takes place under UV-irradiation in benzene as well as benzonitrile to yield the allylic fullerenes, of which the asymmetric version with pinene-derived chiral allylic stannane leads to an enantio-pure fullerene terpenoid.",

author = "Koichi Mikami and Shoji Matsumoto and Takayuki Tonoi and Tomoyoshi Suenobu and Akito Ishida and Shunichi Fukuzumi",

year = "1997",

doi = "10.1055/s-1997-720",

language = "English",

volume = "1997",

pages = "85--87",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

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T1 - Addition Reaction of Allylic Stannanes to the Triplet Excited State of C60 via Photoinduced Electron Transfer Process Leading to Asymmetric Hybridization Chemistry for Fullerene Terpenoid

AU - Mikami, Koichi

AU - Matsumoto, Shoji

AU - Tonoi, Takayuki

AU - Suenobu, Tomoyoshi

AU - Ishida, Akito

AU - Fukuzumi, Shunichi

PY - 1997

Y1 - 1997

N2 - Addition of allylic stannanes to C60 takes place under UV-irradiation in benzene as well as benzonitrile to yield the allylic fullerenes, of which the asymmetric version with pinene-derived chiral allylic stannane leads to an enantio-pure fullerene terpenoid.

AB - Addition of allylic stannanes to C60 takes place under UV-irradiation in benzene as well as benzonitrile to yield the allylic fullerenes, of which the asymmetric version with pinene-derived chiral allylic stannane leads to an enantio-pure fullerene terpenoid.

UR - https://www.scopus.com/pages/publications/0344341615

U2 - 10.1055/s-1997-720

DO - 10.1055/s-1997-720

M3 - Article

AN - SCOPUS:0344341615

SN - 0936-5214

VL - 1997

SP - 85

EP - 87

JO - Synlett

JF - Synlett

IS - 1

ER -

Addition Reaction of Allylic Stannanes to the Triplet Excited State of C60 via Photoinduced Electron Transfer Process Leading to Asymmetric Hybridization Chemistry for Fullerene Terpenoid

Abstract

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Addition Reaction of Allylic Stannanes to the Triplet Excited State of C₆₀ via Photoinduced Electron Transfer Process Leading to Asymmetric Hybridization Chemistry for Fullerene Terpenoid