@article{46767cedc23b41fc86a61a8d195f055e,
title = "Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex",
abstract = "A mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [FeV(NTs)(TAML)]- (1), was oxidized by one-electron oxidants, affording formation of an iron(V)-imido TAML cation radical species, [FeV(NTs)(TAML+•)] (2); 2 is a diamagnetic (S = 0) complex, resulting from the antiferromagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML+•). 2 is a competent oxidant in C-H bond functionalization and nitrene transfer reaction, showing that the reactivity of 2 is greater than that of 1.",
author = "Seungwoo Hong and Xiaoyan Lu and Lee, {Yong Min} and Seo, {Mi Sook} and Takehiro Ohta and Takashi Ogura and Martin Cl{\'e}mancey and Pascale Maldivi and Latour, {Jean Marc} and Ritimukta Sarangi and Wonwoo Nam",
note = "Funding Information: This work was supported by NRF of Korea through CRI (NRF-2012R1A3A2048842 to W.N.), GRL (NRF-2010-00353 to W.N.), Basic Science Research Program (2017R1D1A1B03029982 to Y.M.L.), and MSIP (NRF-2017R1C1B2002037 to S.H.). T.O. acknowledges the support of Grant-in-Aid for Scientific Research (No. 15H00960) by JSPS. J.-M.L. and P.M. were supported by ANR (ANR-11-LABX-003) and GENCI-IDRIS (Grant 2017-A0020807648). XAS data were measured at SSRL and R.S. was supported by NIH P41 grant (P41GM103393) and DOE-BER. Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",
year = "2017",
month = oct,
day = "18",
doi = "10.1021/jacs.7b08161",
language = "English",
volume = "139",
pages = "14372--14375",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "41",
}