A universal chemical potential for sulfur vapours

The unusual chemistry of sulfur is illustrated by the tendency for catenation. Sulfur forms a range of open and closed S_n species in the gas phase, which has led to speculation on the composition of sulfur vapours as a function of temperature and pressure for over a century. Unlike elemental gases such as O₂ and N₂, there is no widely accepted thermodynamic potential for sulfur. Here we combine a first-principles global structure search for the low energy clusters from S₂ to S₈ with a thermodynamic model for the mixed-allotrope system, including the Gibbs free energy for all gas-phase sulfur on an atomic basis. A strongly pressure-dependent transition from a mixture dominant in S₂ to S₈ is identified. A universal chemical potential function, μ_S(T,P), is proposed with wide utility in modelling sulfurisation processes including the formation and annealing of metal chalcogenide semiconductors.