Abstract
A diprotonated form of a cationic water-soluble saddle-distorted porphyrin (H416+) forms stable supramolecular assemblies with multianionic polyoxometalates (POMs) by electrostatic interactions. An assembly of H416+ with a Ru-substituted POM can perform photocatalytic oxidation of organic substrates in water under visible-light irradiation through adduct formation of the H416+ moiety with an oxidant.
Original language | English |
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Pages (from-to) | 1975-1980 |
Number of pages | 6 |
Journal | Green Chemistry |
Volume | 20 |
Issue number | 9 |
DOIs | |
State | Published - 2018 |
Bibliographical note
Publisher Copyright:© 2018 The Royal Society of Chemistry.