A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene

Gaël Ung; Daniel Mendoza-Espinosa; Jean Bouffard; Guy Bertrand

doi:10.1002/anie.201100420

A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene

Gaël Ung, Daniel Mendoza-Espinosa, Jean Bouffard, Guy Bertrand

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

Substitutes you can rely on: Mesoionic carbenes (MICs) are not always stable. However, the acyclic ethynylcarbamodithioate 2 formed (instead of the corresponding MIC) by deprotonation of dithiolium salt 1 underwent cyclization to its precursor under acidic conditions and reacted with a variety of transition-metal centers to yield robust MIC complexes 3; (see scheme; Tipp=2,4,6-triisopropylphenyl).

Original language	English
Pages (from-to)	4215-4218
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	18
DOIs	https://doi.org/10.1002/anie.201100420
State	Published - 26 Apr 2011

Keywords

cyclization
gold
mesoionic carbenes
transition metals

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abstract = "Substitutes you can rely on: Mesoionic carbenes (MICs) are not always stable. However, the acyclic ethynylcarbamodithioate 2 formed (instead of the corresponding MIC) by deprotonation of dithiolium salt 1 underwent cyclization to its precursor under acidic conditions and reacted with a variety of transition-metal centers to yield robust MIC complexes 3; (see scheme; Tipp=2,4,6-triisopropylphenyl).",

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AU - Ung, Gaël

AU - Mendoza-Espinosa, Daniel

AU - Bouffard, Jean

AU - Bertrand, Guy

PY - 2011/4/26

Y1 - 2011/4/26

N2 - Substitutes you can rely on: Mesoionic carbenes (MICs) are not always stable. However, the acyclic ethynylcarbamodithioate 2 formed (instead of the corresponding MIC) by deprotonation of dithiolium salt 1 underwent cyclization to its precursor under acidic conditions and reacted with a variety of transition-metal centers to yield robust MIC complexes 3; (see scheme; Tipp=2,4,6-triisopropylphenyl).

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KW - cyclization

KW - gold

KW - mesoionic carbenes

KW - transition metals

UR - https://www.scopus.com/pages/publications/79955372804

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JF - Angewandte Chemie - International Edition

IS - 18

ER -

A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene

Abstract

Keywords

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