A series of three-dimensional coordination polymers with general formula [{Ln(H2O)n}{Re6Te8(CN)6}] · xH2O (Ln = Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb; n = 3, 4, x = 0, 2.5)

Maria S. Tarasenko; Nikolay G. Naumov; Dmitry Yu Naumov; Sung Jin Kim; Vladimir E. Fedorov

doi:10.1016/j.poly.2008.04.054

A series of three-dimensional coordination polymers with general formula [{Ln(H₂O)_n}{Re₆Te₈(CN)₆}] · xH₂O (Ln = Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb; n = 3, 4, x = 0, 2.5)

Maria S. Tarasenko, Nikolay G. Naumov, Dmitry Yu Naumov, Sung Jin Kim, Vladimir E. Fedorov

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

A series of new compounds containing rare earth cations (Eu to Yb) and paramagnetic cluster anion [Re₆Te₈(CN)₆]^3- was prepared and investigated. The X-ray structural analyses have revealed that the compounds [{Ln(H₂O)₄}{Re₆Te₈(CN)₆}] · 2.5H₂O; Ln = Eu (1), Tb (3), Dy (4), Ho (5), Er (6), Tm (7), [{Gd(H₂O)₃}{Re₆Te₈(CN)₆}] · 2.5H₂O (2) and [{Yb(H₂O)₄}{Re₆Te₈(CN)₆}] (8) are three-dimensional polymers based on Re-CN-Ln interactions. Measurements of magnetic susceptibility for 2 and 5 showed that effective magnetic moment (at 300 K) was 8.13 μ_B for compound 2 and 10.79 μ_B for compound 5 with weak antiferromagnetic ordering appeared at low temperatures.

Original language	English
Pages (from-to)	2357-2364
Number of pages	8
Journal	Polyhedron
Volume	27
Issue number	11
DOIs	https://doi.org/10.1016/j.poly.2008.04.054
State	Published - 4 Aug 2008

Bibliographical note

Funding Information:
This work was supported by the SRC program of the Korea Science and Engineering Foundation (KOSEF) through the Center for Intelligent Nano-Bio Materials at Ewha Womans University (Grant R11-2005-008-03001-0) Rosnauka (2006-Pи-19.0/001/650, Contract No. 02.442.117414) and Russian Foundation of Basic Research (grants 08-03-90413 and 06-03-89503).

Keywords

Coordination framework
Cyanide
Lanthanides
Octahedral cluster
Rhenium

Access to Document

10.1016/j.poly.2008.04.054

Cite this

@article{5f44430b767544dda01cefcf34dc64a7,

title = "A series of three-dimensional coordination polymers with general formula [{Ln(H2O)n}{Re6Te8(CN)6}] · xH2O (Ln = Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb; n = 3, 4, x = 0, 2.5)",

abstract = "A series of new compounds containing rare earth cations (Eu to Yb) and paramagnetic cluster anion [Re6Te8(CN)6]3- was prepared and investigated. The X-ray structural analyses have revealed that the compounds [{Ln(H2O)4}{Re6Te8(CN)6}] · 2.5H2O; Ln = Eu (1), Tb (3), Dy (4), Ho (5), Er (6), Tm (7), [{Gd(H2O)3}{Re6Te8(CN)6}] · 2.5H2O (2) and [{Yb(H2O)4}{Re6Te8(CN)6}] (8) are three-dimensional polymers based on Re-CN-Ln interactions. Measurements of magnetic susceptibility for 2 and 5 showed that effective magnetic moment (at 300 K) was 8.13 μB for compound 2 and 10.79 μB for compound 5 with weak antiferromagnetic ordering appeared at low temperatures.",

keywords = "Coordination framework, Cyanide, Lanthanides, Octahedral cluster, Rhenium",

author = "Tarasenko, {Maria S.} and Naumov, {Nikolay G.} and Naumov, {Dmitry Yu} and Kim, {Sung Jin} and Fedorov, {Vladimir E.}",

note = "Funding Information: This work was supported by the SRC program of the Korea Science and Engineering Foundation (KOSEF) through the Center for Intelligent Nano-Bio Materials at Ewha Womans University (Grant R11-2005-008-03001-0) Rosnauka (2006-Pи-19.0/001/650, Contract No. 02.442.117414) and Russian Foundation of Basic Research (grants 08-03-90413 and 06-03-89503). ",

year = "2008",

month = aug,

day = "4",

doi = "10.1016/j.poly.2008.04.054",

language = "English",

volume = "27",

pages = "2357--2364",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "11",

}

TY - JOUR

T1 - A series of three-dimensional coordination polymers with general formula [{Ln(H2O)n}{Re6Te8(CN)6}] · xH2O (Ln = Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb; n = 3, 4, x = 0, 2.5)

AU - Tarasenko, Maria S.

AU - Naumov, Nikolay G.

AU - Naumov, Dmitry Yu

AU - Kim, Sung Jin

AU - Fedorov, Vladimir E.

N1 - Funding Information: This work was supported by the SRC program of the Korea Science and Engineering Foundation (KOSEF) through the Center for Intelligent Nano-Bio Materials at Ewha Womans University (Grant R11-2005-008-03001-0) Rosnauka (2006-Pи-19.0/001/650, Contract No. 02.442.117414) and Russian Foundation of Basic Research (grants 08-03-90413 and 06-03-89503).

PY - 2008/8/4

Y1 - 2008/8/4

N2 - A series of new compounds containing rare earth cations (Eu to Yb) and paramagnetic cluster anion [Re6Te8(CN)6]3- was prepared and investigated. The X-ray structural analyses have revealed that the compounds [{Ln(H2O)4}{Re6Te8(CN)6}] · 2.5H2O; Ln = Eu (1), Tb (3), Dy (4), Ho (5), Er (6), Tm (7), [{Gd(H2O)3}{Re6Te8(CN)6}] · 2.5H2O (2) and [{Yb(H2O)4}{Re6Te8(CN)6}] (8) are three-dimensional polymers based on Re-CN-Ln interactions. Measurements of magnetic susceptibility for 2 and 5 showed that effective magnetic moment (at 300 K) was 8.13 μB for compound 2 and 10.79 μB for compound 5 with weak antiferromagnetic ordering appeared at low temperatures.

AB - A series of new compounds containing rare earth cations (Eu to Yb) and paramagnetic cluster anion [Re6Te8(CN)6]3- was prepared and investigated. The X-ray structural analyses have revealed that the compounds [{Ln(H2O)4}{Re6Te8(CN)6}] · 2.5H2O; Ln = Eu (1), Tb (3), Dy (4), Ho (5), Er (6), Tm (7), [{Gd(H2O)3}{Re6Te8(CN)6}] · 2.5H2O (2) and [{Yb(H2O)4}{Re6Te8(CN)6}] (8) are three-dimensional polymers based on Re-CN-Ln interactions. Measurements of magnetic susceptibility for 2 and 5 showed that effective magnetic moment (at 300 K) was 8.13 μB for compound 2 and 10.79 μB for compound 5 with weak antiferromagnetic ordering appeared at low temperatures.

KW - Coordination framework

KW - Cyanide

KW - Lanthanides

KW - Octahedral cluster

KW - Rhenium

UR - http://www.scopus.com/inward/record.url?scp=47049131600&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2008.04.054

DO - 10.1016/j.poly.2008.04.054

M3 - Article

AN - SCOPUS:47049131600

SN - 0277-5387

VL - 27

SP - 2357

EP - 2364

JO - Polyhedron

JF - Polyhedron

IS - 11

ER -