A Selective Colorimetric and Fluorometric Chemosensor Based on Conjugated Polydiacetylenes for Cadmium Ion Detection

Thanh Chung Pham; Yong Kyun Kim; Jung Bin Park; Sumin Jeon; Juhyeon Ahn; Yubin Yim; Juyoung Yoon; Songyi Lee

doi:10.1002/cptc.201900165

A Selective Colorimetric and Fluorometric Chemosensor Based on Conjugated Polydiacetylenes for Cadmium Ion Detection

Thanh Chung Pham
, Yong Kyun Kim
, Jung Bin Park
, Sumin Jeon
, Juhyeon Ahn
, Yubin Yim
, Juyoung Yoon
, Songyi Lee

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

In the current study, a polydiacetylene (PDA)-based sensor, derived from a chelidamic acid-picolylamine (CP)-substituted diacetylene monomer, displayed a selective colorimetric and fluorometric change in the presence of cadmium (Cd²⁺) at pH 7.4. The PDA−CP solutions showed a colorimetric change from blue to violet in response to various amounts of Cd²⁺. The chemosensor also showed a rapid fluorescence turn-on response and significant selectivity to Cd²⁺ compared with other metallic cations. The Cd²⁺-selective PDA-based sensor system facilitated the visual detection of Cd²⁺ in aqueous solution. The Cd²⁺ detection limit of PDA−CP was reduced to 1.85×10⁻⁵ M.

Original language	English
Pages (from-to)	1133-1137
Number of pages	5
Journal	ChemPhotoChem
Volume	3
Issue number	11
DOIs	https://doi.org/10.1002/cptc.201900165
State	Published - 1 Nov 2019

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Publisher Copyright:
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Keywords

Schiff bases
cadmium
chemosensors
colorimetric sensors
conjugated polymers

Access to Document

10.1002/cptc.201900165

Cite this

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title = "A Selective Colorimetric and Fluorometric Chemosensor Based on Conjugated Polydiacetylenes for Cadmium Ion Detection",

abstract = "In the current study, a polydiacetylene (PDA)-based sensor, derived from a chelidamic acid-picolylamine (CP)-substituted diacetylene monomer, displayed a selective colorimetric and fluorometric change in the presence of cadmium (Cd2+) at pH 7.4. The PDA−CP solutions showed a colorimetric change from blue to violet in response to various amounts of Cd2+. The chemosensor also showed a rapid fluorescence turn-on response and significant selectivity to Cd2+ compared with other metallic cations. The Cd2+-selective PDA-based sensor system facilitated the visual detection of Cd2+ in aqueous solution. The Cd2+ detection limit of PDA−CP was reduced to 1.85×10−5 M.",

keywords = "Schiff bases, cadmium, chemosensors, colorimetric sensors, conjugated polymers",

author = "Pham, \{Thanh Chung\} and Kim, \{Yong Kyun\} and Park, \{Jung Bin\} and Sumin Jeon and Juhyeon Ahn and Yubin Yim and Juyoung Yoon and Songyi Lee",

note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2019",

month = nov,

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doi = "10.1002/cptc.201900165",

language = "English",

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AU - Pham, Thanh Chung

AU - Kim, Yong Kyun

AU - Park, Jung Bin

AU - Jeon, Sumin

AU - Ahn, Juhyeon

AU - Yim, Yubin

AU - Yoon, Juyoung

AU - Lee, Songyi

PY - 2019/11/1

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N2 - In the current study, a polydiacetylene (PDA)-based sensor, derived from a chelidamic acid-picolylamine (CP)-substituted diacetylene monomer, displayed a selective colorimetric and fluorometric change in the presence of cadmium (Cd2+) at pH 7.4. The PDA−CP solutions showed a colorimetric change from blue to violet in response to various amounts of Cd2+. The chemosensor also showed a rapid fluorescence turn-on response and significant selectivity to Cd2+ compared with other metallic cations. The Cd2+-selective PDA-based sensor system facilitated the visual detection of Cd2+ in aqueous solution. The Cd2+ detection limit of PDA−CP was reduced to 1.85×10−5 M.

AB - In the current study, a polydiacetylene (PDA)-based sensor, derived from a chelidamic acid-picolylamine (CP)-substituted diacetylene monomer, displayed a selective colorimetric and fluorometric change in the presence of cadmium (Cd2+) at pH 7.4. The PDA−CP solutions showed a colorimetric change from blue to violet in response to various amounts of Cd2+. The chemosensor also showed a rapid fluorescence turn-on response and significant selectivity to Cd2+ compared with other metallic cations. The Cd2+-selective PDA-based sensor system facilitated the visual detection of Cd2+ in aqueous solution. The Cd2+ detection limit of PDA−CP was reduced to 1.85×10−5 M.

KW - Schiff bases

KW - cadmium

KW - chemosensors

KW - colorimetric sensors

KW - conjugated polymers

UR - https://www.scopus.com/pages/publications/85087124862

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DO - 10.1002/cptc.201900165

M3 - Article

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JF - ChemPhotoChem

IS - 11

ER -

A Selective Colorimetric and Fluorometric Chemosensor Based on Conjugated Polydiacetylenes for Cadmium Ion Detection

Abstract

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Keywords

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