A novel BF2-chelated azadipyrromethene–fullerene dyad: Synthesis, electrochemistry and photodynamics

Anu N. Amin; Mohamed E. El-Khouly; Navaneetha K. Subbaiyan; Melvin E. Zandler; Shunichi Fukuzumi; Francis D’souza

doi:10.1039/c1cc16071k

A novel BF₂-chelated azadipyrromethene–fullerene dyad: Synthesis, electrochemistry and photodynamics

Anu N. Amin
, Mohamed E. El-Khouly
, Navaneetha K. Subbaiyan
, Melvin E. Zandler
, Shunichi Fukuzumi
, Francis D’souza

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

96 Scopus citations

Abstract

The synthesis, structure, electrochemistry and photodynamics of a BF₂-chelated azadipyrromethene–fullerene dyad are reported in comparison with BF₂-chelated azadipyrromethene without fullerene. The attachment of fullerene resulted in efficient generation of the triplet excited state of the azadipyrromethene via photoinduced electron transfer.

Original language	English
Pages (from-to)	206-208
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	2
DOIs	https://doi.org/10.1039/c1cc16071k
State	Published - 30 Nov 2012

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abstract = "The synthesis, structure, electrochemistry and photodynamics of a BF2-chelated azadipyrromethene–fullerene dyad are reported in comparison with BF2-chelated azadipyrromethene without fullerene. The attachment of fullerene resulted in efficient generation of the triplet excited state of the azadipyrromethene via photoinduced electron transfer.",

author = "Amin, \{Anu N.\} and El-Khouly, \{Mohamed E.\} and Subbaiyan, \{Navaneetha K.\} and Zandler, \{Melvin E.\} and Shunichi Fukuzumi and Francis D{\textquoteright}souza",

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AU - Subbaiyan, Navaneetha K.

AU - Zandler, Melvin E.

AU - Fukuzumi, Shunichi

AU - D’souza, Francis

PY - 2012/11/30

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N2 - The synthesis, structure, electrochemistry and photodynamics of a BF2-chelated azadipyrromethene–fullerene dyad are reported in comparison with BF2-chelated azadipyrromethene without fullerene. The attachment of fullerene resulted in efficient generation of the triplet excited state of the azadipyrromethene via photoinduced electron transfer.

AB - The synthesis, structure, electrochemistry and photodynamics of a BF2-chelated azadipyrromethene–fullerene dyad are reported in comparison with BF2-chelated azadipyrromethene without fullerene. The attachment of fullerene resulted in efficient generation of the triplet excited state of the azadipyrromethene via photoinduced electron transfer.

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ER -

A novel BF2-chelated azadipyrromethene–fullerene dyad: Synthesis, electrochemistry and photodynamics

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A novel BF₂-chelated azadipyrromethene–fullerene dyad: Synthesis, electrochemistry and photodynamics