A nonheme manganese(iv)-oxo species generated in photocatalytic reaction using water as an oxygen source

Xiujuan Wu; Xiaonan Yang; Yong Min Lee; Wonwoo Nam; Licheng Sun

doi:10.1039/c4cc10411k

A nonheme manganese(iv)-oxo species generated in photocatalytic reaction using water as an oxygen source

Xiujuan Wu, Xiaonan Yang, Yong Min Lee, Wonwoo Nam, Licheng Sun

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

A nonheme manganese(iv)-oxo complex, [Mn^IV(O)(BQCN)]²⁺, was generated in the photochemical and chemical oxidation of [Mn^II(BQCN)]²⁺ with water as an oxygen source, respectively. The photocatalytic oxidation of organic substrates, such as alcohol and sulfide, by [Mn^II(BQCN)]²⁺ has been demonstrated in both neutral and acidic media. This journal is

Original language	English
Pages (from-to)	4013-4016
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	19
DOIs	https://doi.org/10.1039/c4cc10411k
State	Published - 7 Mar 2015

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© The Royal Society of Chemistry 2015.

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abstract = "A nonheme manganese(iv)-oxo complex, [MnIV(O)(BQCN)]2+, was generated in the photochemical and chemical oxidation of [MnII(BQCN)]2+ with water as an oxygen source, respectively. The photocatalytic oxidation of organic substrates, such as alcohol and sulfide, by [MnII(BQCN)]2+ has been demonstrated in both neutral and acidic media. This journal is",

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AU - Wu, Xiujuan

AU - Yang, Xiaonan

AU - Lee, Yong Min

AU - Nam, Wonwoo

AU - Sun, Licheng

PY - 2015/3/7

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AB - A nonheme manganese(iv)-oxo complex, [MnIV(O)(BQCN)]2+, was generated in the photochemical and chemical oxidation of [MnII(BQCN)]2+ with water as an oxygen source, respectively. The photocatalytic oxidation of organic substrates, such as alcohol and sulfide, by [MnII(BQCN)]2+ has been demonstrated in both neutral and acidic media. This journal is

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A nonheme manganese(iv)-oxo species generated in photocatalytic reaction using water as an oxygen source

Abstract

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