A nonheme manganese(iv)-oxo species generated in photocatalytic reaction using water as an oxygen source

Xiujuan Wu, Xiaonan Yang, Yong Min Lee, Wonwoo Nam, Licheng Sun

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

A nonheme manganese(iv)-oxo complex, [MnIV(O)(BQCN)]2+, was generated in the photochemical and chemical oxidation of [MnII(BQCN)]2+ with water as an oxygen source, respectively. The photocatalytic oxidation of organic substrates, such as alcohol and sulfide, by [MnII(BQCN)]2+ has been demonstrated in both neutral and acidic media. This journal is

Original languageEnglish
Pages (from-to)4013-4016
Number of pages4
JournalChemical Communications
Volume51
Issue number19
DOIs
StatePublished - 7 Mar 2015

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