A new self-assembled inorganic-organic hybrid layered compound containing hexarhenium cluster: [MV][{Mn(CH3OH)2}{Re6Se8(CN)6}]

Sehye Kim; Youngmee Kim; Junghyun Lee; Woonsup Shin; Minyung Lee; Sung Jin Kim

doi:10.1016/j.ica.2006.09.028

A new self-assembled inorganic-organic hybrid layered compound containing hexarhenium cluster: [MV][{Mn(CH₃OH)₂}{Re₆Se₈(CN)₆}]

Sehye Kim, Youngmee Kim, Junghyun Lee, Woonsup Shin, Minyung Lee, Sung Jin Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A new layered compound, [MV][{Mn(CH₃OH)₂}{Re₆Se₈(CN)₆}] (1) consists of a layer alternately knitted by hexarhenium cluster and Mn complex, and MV²⁺ cations (methyl viologen dication = 1,1′-dimethyl-4,4′-bipyridilium dication) reside between the layers. The title compound 1 is the first layered framework containing cyano-hexarhenium clusters with photoactive guest molecules, MV²⁺. The MV²⁺ can be partly exchanged by H₂TMB²⁺ (N,N,N′,N′-tetramethylbenzidine dication) to form a compound [H₂TMB²⁺]_x[MV²⁺]_1-x [{Mn(CH₃OH)₂}{Re₆Se₈(CN)₆}] (2) showing an electronic interaction between the layered framework and [H₂TMB]²⁺ cation.

Original language	English
Pages (from-to)	1890-1894
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	360
Issue number	6
DOIs	https://doi.org/10.1016/j.ica.2006.09.028
State	Published - 20 Apr 2007

Bibliographical note

Funding Information:
Financial support from the Ministry of Science and Technology (MOST) of KOREA is gratefully acknowledged. W.S. thanks the Grant No. R01-2004-000-10988-0 from the Basic Research Program of the KOSEF.

Keywords

Coordination polymers
Inorganic-organic hybrid materials
Metal clusters
Methyl viologen

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10.1016/j.ica.2006.09.028

Cite this

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title = "A new self-assembled inorganic-organic hybrid layered compound containing hexarhenium cluster: [MV][{Mn(CH3OH)2}{Re6Se8(CN)6}]",

abstract = "A new layered compound, [MV][{Mn(CH3OH)2}{Re6Se8(CN)6}] (1) consists of a layer alternately knitted by hexarhenium cluster and Mn complex, and MV2+ cations (methyl viologen dication = 1,1′-dimethyl-4,4′-bipyridilium dication) reside between the layers. The title compound 1 is the first layered framework containing cyano-hexarhenium clusters with photoactive guest molecules, MV2+. The MV2+ can be partly exchanged by H2TMB2+ (N,N,N′,N′-tetramethylbenzidine dication) to form a compound [H2TMB2+]x[MV2+]1-x [{Mn(CH3OH)2}{Re6Se8(CN)6}] (2) showing an electronic interaction between the layered framework and [H2TMB]2+ cation.",

keywords = "Coordination polymers, Inorganic-organic hybrid materials, Metal clusters, Methyl viologen",

author = "Sehye Kim and Youngmee Kim and Junghyun Lee and Woonsup Shin and Minyung Lee and Kim, {Sung Jin}",

note = "Funding Information: Financial support from the Ministry of Science and Technology (MOST) of KOREA is gratefully acknowledged. W.S. thanks the Grant No. R01-2004-000-10988-0 from the Basic Research Program of the KOSEF. ",

year = "2007",

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doi = "10.1016/j.ica.2006.09.028",

language = "English",

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T2 - [MV][{Mn(CH3OH)2}{Re6Se8(CN)6}]

AU - Kim, Sehye

AU - Kim, Youngmee

AU - Lee, Junghyun

AU - Shin, Woonsup

AU - Lee, Minyung

AU - Kim, Sung Jin

N1 - Funding Information: Financial support from the Ministry of Science and Technology (MOST) of KOREA is gratefully acknowledged. W.S. thanks the Grant No. R01-2004-000-10988-0 from the Basic Research Program of the KOSEF.

PY - 2007/4/20

Y1 - 2007/4/20

N2 - A new layered compound, [MV][{Mn(CH3OH)2}{Re6Se8(CN)6}] (1) consists of a layer alternately knitted by hexarhenium cluster and Mn complex, and MV2+ cations (methyl viologen dication = 1,1′-dimethyl-4,4′-bipyridilium dication) reside between the layers. The title compound 1 is the first layered framework containing cyano-hexarhenium clusters with photoactive guest molecules, MV2+. The MV2+ can be partly exchanged by H2TMB2+ (N,N,N′,N′-tetramethylbenzidine dication) to form a compound [H2TMB2+]x[MV2+]1-x [{Mn(CH3OH)2}{Re6Se8(CN)6}] (2) showing an electronic interaction between the layered framework and [H2TMB]2+ cation.

AB - A new layered compound, [MV][{Mn(CH3OH)2}{Re6Se8(CN)6}] (1) consists of a layer alternately knitted by hexarhenium cluster and Mn complex, and MV2+ cations (methyl viologen dication = 1,1′-dimethyl-4,4′-bipyridilium dication) reside between the layers. The title compound 1 is the first layered framework containing cyano-hexarhenium clusters with photoactive guest molecules, MV2+. The MV2+ can be partly exchanged by H2TMB2+ (N,N,N′,N′-tetramethylbenzidine dication) to form a compound [H2TMB2+]x[MV2+]1-x [{Mn(CH3OH)2}{Re6Se8(CN)6}] (2) showing an electronic interaction between the layered framework and [H2TMB]2+ cation.

KW - Coordination polymers

KW - Inorganic-organic hybrid materials

KW - Metal clusters

KW - Methyl viologen

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