A new organic-inorganic hybrid framework containing octahedral hexarhenium cluster and its transformation by ligand exchange

Sehye Kim; Youngmee Kim; Yunseon Kal; Sung Jin Kim

doi:10.1016/j.ica.2006.09.031

A new organic-inorganic hybrid framework containing octahedral hexarhenium cluster and its transformation by ligand exchange

Sehye Kim, Youngmee Kim, Yunseon Kal, Sung Jin Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

A new organic-inorganic hybrid solid with 3-D framework, [Mn(DMF)₃]₂[Re₆Se₈(CN)₆] (1), has been synthesized and transformed to [H][Mn(salen)]₃[Re₆Se₈(CN)₆] (2) by a ligand exchange. Hexarhenium chalcocyanide clusters are closest packed in cubic symmetry for 1 and rhombohedral symmetry for 2. The manganese complexes in the interstitial sites are three-coordinated to the rhenium cluster in 1 and two-coordinated in 2.

Original language	English
Pages (from-to)	1870-1874
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	360
Issue number	6
DOIs	https://doi.org/10.1016/j.ica.2006.09.031
State	Published - 20 Apr 2007

Bibliographical note

Funding Information:
This work was supported by the Korea Research Foundation Grant (KRF-2004-005-C00093).

Keywords

Coordination polymers
Crystal-to-crystal transformation
Flexible metal-organic frameworks
Hybrid materials
Metal clusters

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10.1016/j.ica.2006.09.031

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title = "A new organic-inorganic hybrid framework containing octahedral hexarhenium cluster and its transformation by ligand exchange",

abstract = "A new organic-inorganic hybrid solid with 3-D framework, [Mn(DMF)3]2[Re6Se8(CN)6] (1), has been synthesized and transformed to [H][Mn(salen)]3[Re6Se8(CN)6] (2) by a ligand exchange. Hexarhenium chalcocyanide clusters are closest packed in cubic symmetry for 1 and rhombohedral symmetry for 2. The manganese complexes in the interstitial sites are three-coordinated to the rhenium cluster in 1 and two-coordinated in 2.",

keywords = "Coordination polymers, Crystal-to-crystal transformation, Flexible metal-organic frameworks, Hybrid materials, Metal clusters",

author = "Sehye Kim and Youngmee Kim and Yunseon Kal and Kim, {Sung Jin}",

note = "Funding Information: This work was supported by the Korea Research Foundation Grant (KRF-2004-005-C00093). ",

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doi = "10.1016/j.ica.2006.09.031",

language = "English",

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journal = "Inorganica Chimica Acta",

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T1 - A new organic-inorganic hybrid framework containing octahedral hexarhenium cluster and its transformation by ligand exchange

AU - Kim, Sehye

AU - Kim, Youngmee

AU - Kal, Yunseon

AU - Kim, Sung Jin

N1 - Funding Information: This work was supported by the Korea Research Foundation Grant (KRF-2004-005-C00093).

PY - 2007/4/20

Y1 - 2007/4/20

N2 - A new organic-inorganic hybrid solid with 3-D framework, [Mn(DMF)3]2[Re6Se8(CN)6] (1), has been synthesized and transformed to [H][Mn(salen)]3[Re6Se8(CN)6] (2) by a ligand exchange. Hexarhenium chalcocyanide clusters are closest packed in cubic symmetry for 1 and rhombohedral symmetry for 2. The manganese complexes in the interstitial sites are three-coordinated to the rhenium cluster in 1 and two-coordinated in 2.

AB - A new organic-inorganic hybrid solid with 3-D framework, [Mn(DMF)3]2[Re6Se8(CN)6] (1), has been synthesized and transformed to [H][Mn(salen)]3[Re6Se8(CN)6] (2) by a ligand exchange. Hexarhenium chalcocyanide clusters are closest packed in cubic symmetry for 1 and rhombohedral symmetry for 2. The manganese complexes in the interstitial sites are three-coordinated to the rhenium cluster in 1 and two-coordinated in 2.

KW - Coordination polymers

KW - Crystal-to-crystal transformation

KW - Flexible metal-organic frameworks

KW - Hybrid materials

KW - Metal clusters

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DO - 10.1016/j.ica.2006.09.031

M3 - Article

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SN - 0020-1693

VL - 360

SP - 1870

EP - 1874

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 6

ER -

A new organic-inorganic hybrid framework containing octahedral hexarhenium cluster and its transformation by ligand exchange

Abstract

Bibliographical note

Keywords

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