A new organic-inorganic hybrid framework containing octahedral hexarhenium cluster and its transformation by ligand exchange

Sehye Kim, Youngmee Kim, Yunseon Kal, Sung Jin Kim

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

A new organic-inorganic hybrid solid with 3-D framework, [Mn(DMF)3]2[Re6Se8(CN)6] (1), has been synthesized and transformed to [H][Mn(salen)]3[Re6Se8(CN)6] (2) by a ligand exchange. Hexarhenium chalcocyanide clusters are closest packed in cubic symmetry for 1 and rhombohedral symmetry for 2. The manganese complexes in the interstitial sites are three-coordinated to the rhenium cluster in 1 and two-coordinated in 2.

Original languageEnglish
Pages (from-to)1870-1874
Number of pages5
JournalInorganica Chimica Acta
Volume360
Issue number6
DOIs
StatePublished - 20 Apr 2007

Keywords

  • Coordination polymers
  • Crystal-to-crystal transformation
  • Flexible metal-organic frameworks
  • Hybrid materials
  • Metal clusters

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