@article{2d3d994e2a1249e38d036beca08929b9,
title = "A new hexanuclear rhenium cluster complex with six terminal acetate ligands: Synthesis, structure, and properties of K4Re 6S8(CH3COO)6 · H2O",
abstract = "A room-temperature reaction between [Re6S8(OH) 6]4- and acetic acid in an aqueous solution resulted in the substitution of all terminal hydroxo groups by acetate ligands, affording a new hexanuclear anionic rhenium cluster complex [Re6S 8(CH3COO)6]4-. The complex was isolated as a potassium salt with the composition of K4[Re 6S8(CH3COO)6].8H2O (1) and characterized by X-ray single-crystal diffraction and elemental analyses, IR, 1H NMR, UV-Vis, and luminescence spectroscopies.",
keywords = "Carboxylate ligands, Cluster compounds, Luminescence, Rhenium, Synthesis",
author = "Brylev, {Konstantin A.} and Mironov, {Yuri V.} and Fedorov, {Vladimir E.} and Kim, {Sung Jin} and Pietzsch, {Hans J{\"u}rgen} and Holger Stephan and Akitaka Ito and Noboru Kitamura",
note = "Funding Information: This research was supported by the Russian Foundation for Basic Research (Grants 09-03-92100 , 09-03-92004 ), by the Interdisciplinary Integration Project of SB RAS No. 76, by National Research Foundation of Korea Grant funded by the Korean Government ( 20090063004 ), and by the Bundesministerium f{\"u}r Bildung and Forschung ( WTZ-Projekt RUS 07/005 ). Also K.A. Brylev thanks the Japan Society for the Promotion of Science (JSPS) for a Post Doctoral Fellowship for Foreign Researchers. ",
year = "2010",
month = aug,
day = "10",
doi = "10.1016/j.ica.2010.04.042",
language = "English",
volume = "363",
pages = "2686--2691",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier BV",
number = "11",
}