A new hexanuclear rhenium cluster complex with six terminal acetate ligands: Synthesis, structure, and properties of K4Re 6S8(CH3COO)6 · H2O

Konstantin A. Brylev; Yuri V. Mironov; Vladimir E. Fedorov; Sung Jin Kim; Hans Jürgen Pietzsch; Holger Stephan; Akitaka Ito; Noboru Kitamura

doi:10.1016/j.ica.2010.04.042

A new hexanuclear rhenium cluster complex with six terminal acetate ligands: Synthesis, structure, and properties of K₄Re ₆S₈(CH₃COO)₆ · H₂O

Konstantin A. Brylev, Yuri V. Mironov, Vladimir E. Fedorov, Sung Jin Kim, Hans Jürgen Pietzsch, Holger Stephan, Akitaka Ito, Noboru Kitamura

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

A room-temperature reaction between [Re₆S₈(OH) ₆]^4- and acetic acid in an aqueous solution resulted in the substitution of all terminal hydroxo groups by acetate ligands, affording a new hexanuclear anionic rhenium cluster complex [Re₆S ₈(CH₃COO)₆]^4-. The complex was isolated as a potassium salt with the composition of K₄[Re ₆S₈(CH₃COO)₆].8H₂O (1) and characterized by X-ray single-crystal diffraction and elemental analyses, IR, ¹H NMR, UV-Vis, and luminescence spectroscopies.

Original language	English
Pages (from-to)	2686-2691
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	363
Issue number	11
DOIs	https://doi.org/10.1016/j.ica.2010.04.042
State	Published - 10 Aug 2010

Bibliographical note

Funding Information:
This research was supported by the Russian Foundation for Basic Research (Grants 09-03-92100 , 09-03-92004 ), by the Interdisciplinary Integration Project of SB RAS No. 76, by National Research Foundation of Korea Grant funded by the Korean Government ( 20090063004 ), and by the Bundesministerium für Bildung and Forschung ( WTZ-Projekt RUS 07/005 ). Also K.A. Brylev thanks the Japan Society for the Promotion of Science (JSPS) for a Post Doctoral Fellowship for Foreign Researchers.

Keywords

Carboxylate ligands
Cluster compounds
Luminescence
Rhenium
Synthesis

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10.1016/j.ica.2010.04.042

Cite this

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title = "A new hexanuclear rhenium cluster complex with six terminal acetate ligands: Synthesis, structure, and properties of K4Re 6S8(CH3COO)6 · H2O",

abstract = "A room-temperature reaction between [Re6S8(OH) 6]4- and acetic acid in an aqueous solution resulted in the substitution of all terminal hydroxo groups by acetate ligands, affording a new hexanuclear anionic rhenium cluster complex [Re6S 8(CH3COO)6]4-. The complex was isolated as a potassium salt with the composition of K4[Re 6S8(CH3COO)6].8H2O (1) and characterized by X-ray single-crystal diffraction and elemental analyses, IR, 1H NMR, UV-Vis, and luminescence spectroscopies.",

keywords = "Carboxylate ligands, Cluster compounds, Luminescence, Rhenium, Synthesis",

author = "Brylev, {Konstantin A.} and Mironov, {Yuri V.} and Fedorov, {Vladimir E.} and Kim, {Sung Jin} and Pietzsch, {Hans J{\"u}rgen} and Holger Stephan and Akitaka Ito and Noboru Kitamura",

note = "Funding Information: This research was supported by the Russian Foundation for Basic Research (Grants 09-03-92100 , 09-03-92004 ), by the Interdisciplinary Integration Project of SB RAS No. 76, by National Research Foundation of Korea Grant funded by the Korean Government ( 20090063004 ), and by the Bundesministerium f{\"u}r Bildung and Forschung ( WTZ-Projekt RUS 07/005 ). Also K.A. Brylev thanks the Japan Society for the Promotion of Science (JSPS) for a Post Doctoral Fellowship for Foreign Researchers. ",

year = "2010",

month = aug,

day = "10",

doi = "10.1016/j.ica.2010.04.042",

language = "English",

volume = "363",

pages = "2686--2691",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

number = "11",

}

TY - JOUR

T1 - A new hexanuclear rhenium cluster complex with six terminal acetate ligands

T2 - Synthesis, structure, and properties of K4Re 6S8(CH3COO)6 · H2O

AU - Brylev, Konstantin A.

AU - Mironov, Yuri V.

AU - Fedorov, Vladimir E.

AU - Kim, Sung Jin

AU - Pietzsch, Hans Jürgen

AU - Stephan, Holger

AU - Ito, Akitaka

AU - Kitamura, Noboru

N1 - Funding Information: This research was supported by the Russian Foundation for Basic Research (Grants 09-03-92100 , 09-03-92004 ), by the Interdisciplinary Integration Project of SB RAS No. 76, by National Research Foundation of Korea Grant funded by the Korean Government ( 20090063004 ), and by the Bundesministerium für Bildung and Forschung ( WTZ-Projekt RUS 07/005 ). Also K.A. Brylev thanks the Japan Society for the Promotion of Science (JSPS) for a Post Doctoral Fellowship for Foreign Researchers.

PY - 2010/8/10

Y1 - 2010/8/10

N2 - A room-temperature reaction between [Re6S8(OH) 6]4- and acetic acid in an aqueous solution resulted in the substitution of all terminal hydroxo groups by acetate ligands, affording a new hexanuclear anionic rhenium cluster complex [Re6S 8(CH3COO)6]4-. The complex was isolated as a potassium salt with the composition of K4[Re 6S8(CH3COO)6].8H2O (1) and characterized by X-ray single-crystal diffraction and elemental analyses, IR, 1H NMR, UV-Vis, and luminescence spectroscopies.

AB - A room-temperature reaction between [Re6S8(OH) 6]4- and acetic acid in an aqueous solution resulted in the substitution of all terminal hydroxo groups by acetate ligands, affording a new hexanuclear anionic rhenium cluster complex [Re6S 8(CH3COO)6]4-. The complex was isolated as a potassium salt with the composition of K4[Re 6S8(CH3COO)6].8H2O (1) and characterized by X-ray single-crystal diffraction and elemental analyses, IR, 1H NMR, UV-Vis, and luminescence spectroscopies.

KW - Carboxylate ligands

KW - Cluster compounds

KW - Luminescence

KW - Rhenium

KW - Synthesis

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