A new Co(II) complex with N,O-donor Schiff base: Synthesis, structure and characterization

L. Xu; Yu V. Mironov; X. Qi; S. J. Kim

doi:10.1007/s10947-006-0418-1

A new Co(II) complex with N,O-donor Schiff base: Synthesis, structure and characterization

L. Xu, Yu V. Mironov, X. Qi, S. J. Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

A new Co(II) complex with tridentate Schiff base ligand with a N,N,O donor set has been synthesized and characterized by single X-ray technique and spectroscopic techniques. The thermochemical properties have been studied. X-ray structure analysis of the title compound Co(II)L₂ [HL = 2-methyl-6-(2′-hydroxybenzylideneamino) pyridine] shows that the polyhedron around Co(II) is a distorted tetrahedron, and the self-assembly via intermolecular π-π interactions leads to a three-dimensional network. Crystal data for the title complex C₂₆H₂₂CoN ₄O₂: Monoclinic, space group Ia, a = 11.741(7) Å, b = 8.149(5) Å, c = 22.764(16) Å, β = 98.530(12)°, V = 2154(2) Å³, Z = 4.

Original language	English
Pages (from-to)	998-1001
Number of pages	4
Journal	Journal of Structural Chemistry
Volume	47
Issue number	5
DOIs	https://doi.org/10.1007/s10947-006-0418-1
State	Published - Sep 2006

Bibliographical note

Funding Information:
This work was supported by the Korea Research Foundation Grant (KRF — 2004 — 005 — C00093), Research Innovation Program of Nanjing Forestry University, P. R. China (CX03-070-1) and Research Foundation for Talent of Nanjing Forestry University, P. R. China.

Keywords

Co(II) complex
Crystal structure
Schiff base ligand
Weight loss

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10.1007/s10947-006-0418-1

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title = "A new Co(II) complex with N,O-donor Schiff base: Synthesis, structure and characterization",

abstract = "A new Co(II) complex with tridentate Schiff base ligand with a N,N,O donor set has been synthesized and characterized by single X-ray technique and spectroscopic techniques. The thermochemical properties have been studied. X-ray structure analysis of the title compound Co(II)L2 [HL = 2-methyl-6-(2′-hydroxybenzylideneamino) pyridine] shows that the polyhedron around Co(II) is a distorted tetrahedron, and the self-assembly via intermolecular π-π interactions leads to a three-dimensional network. Crystal data for the title complex C26H22CoN 4O2: Monoclinic, space group Ia, a = 11.741(7) {\AA}, b = 8.149(5) {\AA}, c = 22.764(16) {\AA}, β = 98.530(12)°, V = 2154(2) {\AA}3, Z = 4.",

keywords = "Co(II) complex, Crystal structure, Schiff base ligand, Weight loss",

author = "L. Xu and Mironov, {Yu V.} and X. Qi and Kim, {S. J.}",

note = "Funding Information: This work was supported by the Korea Research Foundation Grant (KRF — 2004 — 005 — C00093), Research Innovation Program of Nanjing Forestry University, P. R. China (CX03-070-1) and Research Foundation for Talent of Nanjing Forestry University, P. R. China.",

year = "2006",

month = sep,

doi = "10.1007/s10947-006-0418-1",

language = "English",

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T2 - Synthesis, structure and characterization

AU - Xu, L.

AU - Mironov, Yu V.

AU - Qi, X.

AU - Kim, S. J.

N1 - Funding Information: This work was supported by the Korea Research Foundation Grant (KRF — 2004 — 005 — C00093), Research Innovation Program of Nanjing Forestry University, P. R. China (CX03-070-1) and Research Foundation for Talent of Nanjing Forestry University, P. R. China.

PY - 2006/9

Y1 - 2006/9

N2 - A new Co(II) complex with tridentate Schiff base ligand with a N,N,O donor set has been synthesized and characterized by single X-ray technique and spectroscopic techniques. The thermochemical properties have been studied. X-ray structure analysis of the title compound Co(II)L2 [HL = 2-methyl-6-(2′-hydroxybenzylideneamino) pyridine] shows that the polyhedron around Co(II) is a distorted tetrahedron, and the self-assembly via intermolecular π-π interactions leads to a three-dimensional network. Crystal data for the title complex C26H22CoN 4O2: Monoclinic, space group Ia, a = 11.741(7) Å, b = 8.149(5) Å, c = 22.764(16) Å, β = 98.530(12)°, V = 2154(2) Å3, Z = 4.

AB - A new Co(II) complex with tridentate Schiff base ligand with a N,N,O donor set has been synthesized and characterized by single X-ray technique and spectroscopic techniques. The thermochemical properties have been studied. X-ray structure analysis of the title compound Co(II)L2 [HL = 2-methyl-6-(2′-hydroxybenzylideneamino) pyridine] shows that the polyhedron around Co(II) is a distorted tetrahedron, and the self-assembly via intermolecular π-π interactions leads to a three-dimensional network. Crystal data for the title complex C26H22CoN 4O2: Monoclinic, space group Ia, a = 11.741(7) Å, b = 8.149(5) Å, c = 22.764(16) Å, β = 98.530(12)°, V = 2154(2) Å3, Z = 4.

KW - Co(II) complex

KW - Crystal structure

KW - Schiff base ligand

KW - Weight loss

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DO - 10.1007/s10947-006-0418-1

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JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

IS - 5

ER -

A new Co(II) complex with N,O-donor Schiff base: Synthesis, structure and characterization

Abstract

Bibliographical note

Keywords

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