A new Co(II) complex with N,O-donor Schiff base: Synthesis, structure and characterization

L. Xu, Yu V. Mironov, X. Qi, S. J. Kim

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

A new Co(II) complex with tridentate Schiff base ligand with a N,N,O donor set has been synthesized and characterized by single X-ray technique and spectroscopic techniques. The thermochemical properties have been studied. X-ray structure analysis of the title compound Co(II)L2 [HL = 2-methyl-6-(2′-hydroxybenzylideneamino) pyridine] shows that the polyhedron around Co(II) is a distorted tetrahedron, and the self-assembly via intermolecular π-π interactions leads to a three-dimensional network. Crystal data for the title complex C26H22CoN 4O2: Monoclinic, space group Ia, a = 11.741(7) Å, b = 8.149(5) Å, c = 22.764(16) Å, β = 98.530(12)°, V = 2154(2) Å3, Z = 4.

Original languageEnglish
Pages (from-to)998-1001
Number of pages4
JournalJournal of Structural Chemistry
Volume47
Issue number5
DOIs
StatePublished - Sep 2006

Keywords

  • Co(II) complex
  • Crystal structure
  • Schiff base ligand
  • Weight loss

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