TY - JOUR
T1 - A new Co(II) complex with N,O-donor Schiff base
T2 - Synthesis, structure and characterization
AU - Xu, L.
AU - Mironov, Yu V.
AU - Qi, X.
AU - Kim, S. J.
N1 - Funding Information:
This work was supported by the Korea Research Foundation Grant (KRF — 2004 — 005 — C00093), Research Innovation Program of Nanjing Forestry University, P. R. China (CX03-070-1) and Research Foundation for Talent of Nanjing Forestry University, P. R. China.
PY - 2006/9
Y1 - 2006/9
N2 - A new Co(II) complex with tridentate Schiff base ligand with a N,N,O donor set has been synthesized and characterized by single X-ray technique and spectroscopic techniques. The thermochemical properties have been studied. X-ray structure analysis of the title compound Co(II)L2 [HL = 2-methyl-6-(2′-hydroxybenzylideneamino) pyridine] shows that the polyhedron around Co(II) is a distorted tetrahedron, and the self-assembly via intermolecular π-π interactions leads to a three-dimensional network. Crystal data for the title complex C26H22CoN 4O2: Monoclinic, space group Ia, a = 11.741(7) Å, b = 8.149(5) Å, c = 22.764(16) Å, β = 98.530(12)°, V = 2154(2) Å3, Z = 4.
AB - A new Co(II) complex with tridentate Schiff base ligand with a N,N,O donor set has been synthesized and characterized by single X-ray technique and spectroscopic techniques. The thermochemical properties have been studied. X-ray structure analysis of the title compound Co(II)L2 [HL = 2-methyl-6-(2′-hydroxybenzylideneamino) pyridine] shows that the polyhedron around Co(II) is a distorted tetrahedron, and the self-assembly via intermolecular π-π interactions leads to a three-dimensional network. Crystal data for the title complex C26H22CoN 4O2: Monoclinic, space group Ia, a = 11.741(7) Å, b = 8.149(5) Å, c = 22.764(16) Å, β = 98.530(12)°, V = 2154(2) Å3, Z = 4.
KW - Co(II) complex
KW - Crystal structure
KW - Schiff base ligand
KW - Weight loss
UR - http://www.scopus.com/inward/record.url?scp=33847290899&partnerID=8YFLogxK
U2 - 10.1007/s10947-006-0418-1
DO - 10.1007/s10947-006-0418-1
M3 - Article
AN - SCOPUS:33847290899
VL - 47
SP - 998
EP - 1001
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 5
ER -