Abstract
A new Co(II) complex with tridentate Schiff base ligand with a N,N,O donor set has been synthesized and characterized by single X-ray technique and spectroscopic techniques. The thermochemical properties have been studied. X-ray structure analysis of the title compound Co(II)L2 [HL = 2-methyl-6-(2′-hydroxybenzylideneamino) pyridine] shows that the polyhedron around Co(II) is a distorted tetrahedron, and the self-assembly via intermolecular π-π interactions leads to a three-dimensional network. Crystal data for the title complex C26H22CoN 4O2: Monoclinic, space group Ia, a = 11.741(7) Å, b = 8.149(5) Å, c = 22.764(16) Å, β = 98.530(12)°, V = 2154(2) Å3, Z = 4.
Original language | English |
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Pages (from-to) | 998-1001 |
Number of pages | 4 |
Journal | Journal of Structural Chemistry |
Volume | 47 |
Issue number | 5 |
DOIs | |
State | Published - Sep 2006 |
Bibliographical note
Funding Information:This work was supported by the Korea Research Foundation Grant (KRF — 2004 — 005 — C00093), Research Innovation Program of Nanjing Forestry University, P. R. China (CX03-070-1) and Research Foundation for Talent of Nanjing Forestry University, P. R. China.
Keywords
- Co(II) complex
- Crystal structure
- Schiff base ligand
- Weight loss