Abstract
As a new strategy for the optimization of a chiral catalyst, the catalytic activity of the host-guest complexes of chiral bisphosphine bearing imidazolidinone was investigated in Rh-catalyzed asymmetric hydrogenation of enamide. Marginal enhancement in enantioselectivity was observed and the nature of interaction between host-guest was experimentally elucidated.
| Original language | English |
|---|---|
| Pages (from-to) | 635-638 |
| Number of pages | 4 |
| Journal | Bulletin of the Korean Chemical Society |
| Volume | 31 |
| Issue number | 3 |
| DOIs | |
| State | Published - Mar 2010 |
Keywords
- Catalyst optimization
- Chiral catalyst
- Host/guest
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