A new approch for catalyst optimization: Host/guest complexes of chiral bisphosphine bearing imidazolidinone and their application in Rh-catalyzed asymmetric hydrogenation

Jung Hwan Park; Hyunik Shin; Doo Han Park; Sang Gi Lee

doi:10.5012/bkcs.2010.31.03.635

A new approch for catalyst optimization: Host/guest complexes of chiral bisphosphine bearing imidazolidinone and their application in Rh-catalyzed asymmetric hydrogenation

Jung Hwan Park, Hyunik Shin, Doo Han Park, Sang Gi Lee

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

As a new strategy for the optimization of a chiral catalyst, the catalytic activity of the host-guest complexes of chiral bisphosphine bearing imidazolidinone was investigated in Rh-catalyzed asymmetric hydrogenation of enamide. Marginal enhancement in enantioselectivity was observed and the nature of interaction between host-guest was experimentally elucidated.

Original language	English
Pages (from-to)	635-638
Number of pages	4
Journal	Bulletin of the Korean Chemical Society
Volume	31
Issue number	3
DOIs	https://doi.org/10.5012/bkcs.2010.31.03.635
State	Published - Mar 2010

Keywords

Catalyst optimization
Chiral catalyst
Host/guest

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10.5012/bkcs.2010.31.03.635

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abstract = "As a new strategy for the optimization of a chiral catalyst, the catalytic activity of the host-guest complexes of chiral bisphosphine bearing imidazolidinone was investigated in Rh-catalyzed asymmetric hydrogenation of enamide. Marginal enhancement in enantioselectivity was observed and the nature of interaction between host-guest was experimentally elucidated.",

keywords = "Catalyst optimization, Chiral catalyst, Host/guest",

author = "Park, {Jung Hwan} and Hyunik Shin and Park, {Doo Han} and Lee, {Sang Gi}",

year = "2010",

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language = "English",

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pages = "635--638",

journal = "Bulletin of the Korean Chemical Society",

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A new approch for catalyst optimization: Host/guest complexes of chiral bisphosphine bearing imidazolidinone and their application in Rh-catalyzed asymmetric hydrogenation. / Park, Jung Hwan; Shin, Hyunik; Park, Doo Han et al.
In: Bulletin of the Korean Chemical Society, Vol. 31, No. 3, 03.2010, p. 635-638.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A new approch for catalyst optimization

T2 - Host/guest complexes of chiral bisphosphine bearing imidazolidinone and their application in Rh-catalyzed asymmetric hydrogenation

AU - Park, Jung Hwan

AU - Shin, Hyunik

AU - Park, Doo Han

AU - Lee, Sang Gi

PY - 2010/3

Y1 - 2010/3

N2 - As a new strategy for the optimization of a chiral catalyst, the catalytic activity of the host-guest complexes of chiral bisphosphine bearing imidazolidinone was investigated in Rh-catalyzed asymmetric hydrogenation of enamide. Marginal enhancement in enantioselectivity was observed and the nature of interaction between host-guest was experimentally elucidated.

AB - As a new strategy for the optimization of a chiral catalyst, the catalytic activity of the host-guest complexes of chiral bisphosphine bearing imidazolidinone was investigated in Rh-catalyzed asymmetric hydrogenation of enamide. Marginal enhancement in enantioselectivity was observed and the nature of interaction between host-guest was experimentally elucidated.

KW - Catalyst optimization

KW - Chiral catalyst

KW - Host/guest

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U2 - 10.5012/bkcs.2010.31.03.635

DO - 10.5012/bkcs.2010.31.03.635

M3 - Article

AN - SCOPUS:77951771647

SN - 0253-2964

VL - 31

SP - 635

EP - 638

JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

IS - 3

ER -

A new approch for catalyst optimization: Host/guest complexes of chiral bisphosphine bearing imidazolidinone and their application in Rh-catalyzed asymmetric hydrogenation

Abstract

Keywords

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