A naphthalimide-calixarene as a two-faced and highly selective fluorescent chemosensor for Cu2+ or F-

Zhaochao Xu; Suki Kim; Ha Na Kim; Su Jung Han; Chongmok Lee; Jong Seung Kim; Xuhong Qian; Juyoung Yoon

doi:10.1016/j.tetlet.2007.10.109

A naphthalimide-calixarene as a two-faced and highly selective fluorescent chemosensor for Cu²⁺ or F^-

Zhaochao Xu, Suki Kim, Ha Na Kim, Su Jung Han, Chongmok Lee, Jong Seung Kim, Xuhong Qian, Juyoung Yoon

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

109 Scopus citations

Abstract

A new naphthalimide-calix[4]arene was synthesized as a two-faced and highly selective fluorescent chemosensor for Cu²⁺ or F^-. This chemosensor displayed a selective fluorescence quenching effect only with Cu²⁺ among the various metal ions. On the other hand, among the various anions, the title chemosensor displayed a selective fluorescence quenching effect only with F^-. The binding mode with F^- was further investigated using fluorescence changes and ¹H NMR experiments.

Original language	English
Pages (from-to)	9151-9154
Number of pages	4
Journal	Tetrahedron Letters
Volume	48
Issue number	52
DOIs	https://doi.org/10.1016/j.tetlet.2007.10.109
State	Published - 24 Dec 2007

Bibliographical note

Funding Information:
This work was supported by the Korea Science and Engineering Foundation (KOSEF) grant funded by the Korean government (MOST) (NRL; R04-2007-000-2007-0), the Basic Science Research of KOSEF (R01-2006-000-10001-0), and BK21.

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10.1016/j.tetlet.2007.10.109

Cite this

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title = "A naphthalimide-calixarene as a two-faced and highly selective fluorescent chemosensor for Cu2+ or F-",

abstract = "A new naphthalimide-calix[4]arene was synthesized as a two-faced and highly selective fluorescent chemosensor for Cu2+ or F-. This chemosensor displayed a selective fluorescence quenching effect only with Cu2+ among the various metal ions. On the other hand, among the various anions, the title chemosensor displayed a selective fluorescence quenching effect only with F-. The binding mode with F- was further investigated using fluorescence changes and 1H NMR experiments.",

author = "Zhaochao Xu and Suki Kim and Kim, {Ha Na} and Han, {Su Jung} and Chongmok Lee and Kim, {Jong Seung} and Xuhong Qian and Juyoung Yoon",

note = "Funding Information: This work was supported by the Korea Science and Engineering Foundation (KOSEF) grant funded by the Korean government (MOST) (NRL; R04-2007-000-2007-0), the Basic Science Research of KOSEF (R01-2006-000-10001-0), and BK21. ",

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T1 - A naphthalimide-calixarene as a two-faced and highly selective fluorescent chemosensor for Cu2+ or F-

AU - Xu, Zhaochao

AU - Kim, Suki

AU - Kim, Ha Na

AU - Han, Su Jung

AU - Lee, Chongmok

AU - Kim, Jong Seung

AU - Qian, Xuhong

AU - Yoon, Juyoung

N1 - Funding Information: This work was supported by the Korea Science and Engineering Foundation (KOSEF) grant funded by the Korean government (MOST) (NRL; R04-2007-000-2007-0), the Basic Science Research of KOSEF (R01-2006-000-10001-0), and BK21.

PY - 2007/12/24

Y1 - 2007/12/24

N2 - A new naphthalimide-calix[4]arene was synthesized as a two-faced and highly selective fluorescent chemosensor for Cu2+ or F-. This chemosensor displayed a selective fluorescence quenching effect only with Cu2+ among the various metal ions. On the other hand, among the various anions, the title chemosensor displayed a selective fluorescence quenching effect only with F-. The binding mode with F- was further investigated using fluorescence changes and 1H NMR experiments.

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