A Mononuclear Nonheme Iron(V)-Imido Complex

Seungwoo Hong; Kyle D. Sutherlin; Anil Kumar Vardhaman; James J. Yan; Sora Park; Yong Min Lee; Soojeong Jang; Xiaoyan Lu; Takehiro Ohta; Takashi Ogura; Edward I. Solomon; Wonwoo Nam

doi:10.1021/jacs.7b04695

A Mononuclear Nonheme Iron(V)-Imido Complex

Seungwoo Hong
, Kyle D. Sutherlin
, Anil Kumar Vardhaman
, James J. Yan
, Sora Park
, Yong Min Lee
, Soojeong Jang
, Xiaoyan Lu
, Takehiro Ohta
, Takashi Ogura
, Edward I. Solomon
, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)Fe^V(NTs)]^? (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe - N bond length of 1.65(4) Å, and an Fe - N vibration at 817 cm^-1. The reactivity of 1 was demonstrated in C - H bond functionalization and nitrene transfer reactions.

Original language	English
Pages (from-to)	8800-8803
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	139
Issue number	26
DOIs	https://doi.org/10.1021/jacs.7b04695
State	Published - 5 Jul 2017

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© 2017 American Chemical Society.

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title = "A Mononuclear Nonheme Iron(V)-Imido Complex",

abstract = "Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)FeV(NTs)]? (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe - N bond length of 1.65(4) {\AA}, and an Fe - N vibration at 817 cm-1. The reactivity of 1 was demonstrated in C - H bond functionalization and nitrene transfer reactions.",

author = "Seungwoo Hong and Sutherlin, \{Kyle D.\} and Vardhaman, \{Anil Kumar\} and Yan, \{James J.\} and Sora Park and Lee, \{Yong Min\} and Soojeong Jang and Xiaoyan Lu and Takehiro Ohta and Takashi Ogura and Solomon, \{Edward I.\} and Wonwoo Nam",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

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doi = "10.1021/jacs.7b04695",

language = "English",

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T1 - A Mononuclear Nonheme Iron(V)-Imido Complex

AU - Hong, Seungwoo

AU - Sutherlin, Kyle D.

AU - Vardhaman, Anil Kumar

AU - Yan, James J.

AU - Park, Sora

AU - Lee, Yong Min

AU - Jang, Soojeong

AU - Lu, Xiaoyan

AU - Ohta, Takehiro

AU - Ogura, Takashi

AU - Solomon, Edward I.

AU - Nam, Wonwoo

PY - 2017/7/5

Y1 - 2017/7/5

N2 - Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)FeV(NTs)]? (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe - N bond length of 1.65(4) Å, and an Fe - N vibration at 817 cm-1. The reactivity of 1 was demonstrated in C - H bond functionalization and nitrene transfer reactions.

AB - Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)FeV(NTs)]? (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe - N bond length of 1.65(4) Å, and an Fe - N vibration at 817 cm-1. The reactivity of 1 was demonstrated in C - H bond functionalization and nitrene transfer reactions.

UR - https://www.scopus.com/pages/publications/85022056323

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DO - 10.1021/jacs.7b04695

M3 - Article

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AN - SCOPUS:85022056323

SN - 0002-7863

VL - 139

SP - 8800

EP - 8803

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 26

ER -

A Mononuclear Nonheme Iron(V)-Imido Complex

Abstract

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