@article{e9de3e2c01e748898a179a449ca443ab,
title = "A Mononuclear Nonheme Iron(V)-Imido Complex",
abstract = "Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)FeV(NTs)]? (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe - N bond length of 1.65(4) {\AA}, and an Fe - N vibration at 817 cm-1. The reactivity of 1 was demonstrated in C - H bond functionalization and nitrene transfer reactions.",
author = "Seungwoo Hong and Sutherlin, {Kyle D.} and Vardhaman, {Anil Kumar} and Yan, {James J.} and Sora Park and Lee, {Yong Min} and Soojeong Jang and Xiaoyan Lu and Takehiro Ohta and Takashi Ogura and Solomon, {Edward I.} and Wonwoo Nam",
note = "Funding Information: This work was supported by NRF of Korea through CRI (NRF-2012R1A3A2048842 to W.N.), GRL (NRF-2010-00353 to W.N.), MSIP (NRF-2017R1C1B2002037 to S.H.), and Sookmyung Women's University Grants (1-1603-2054 to S.H.). Funding for this work was also provided by the NIH (GM-40392 to E.I.S.). T.O. acknowledges the support of {"}Strategic Young Researcher Overseas Visits Program for Accelerating Brain Circulation{"} and Grant-in-Aid for Scientific Research (No. 15H00960) by JSPS. Use of the SSRL, SLAC National Accelerator Laboratory, is supported by the U.S. DOE under Contract No. DE-AC02-76SF00515. Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",
year = "2017",
month = jul,
day = "5",
doi = "10.1021/jacs.7b04695",
language = "English",
volume = "139",
pages = "8800--8803",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "26",
}