@article{0845a0cc77d14156b73ee29c6183a52d,
title = "A Mononuclear Nonheme Iron(IV)-Amido Complex Relevant for the Compound II Chemistry of Cytochrome P450",
abstract = " A mononuclear nonheme iron(IV)-amido complex bearing a tetraamido macrocyclic ligand, [(TAML)Fe IV (NHTs)] - (1), was synthesized via a hydrogen atom (H atom) abstraction reaction of an iron(V)-imido complex, [(TAML)Fe V (NTs)] - (2), and fully characterized using various spectroscopies. We then investigated (1) the pK a of 1, (2) the reaction of 1 with a carbon-centered radical, and (3) the H atom abstraction reaction of 1. To the best of our knowledge, the present study reports for the first time the synthesis and chemical properties/reactions of a high-valent iron(IV)-amido complex.",
author = "Xiaoyan Lu and Li, {Xiao Xi} and Seo, {Mi Sook} and Lee, {Yong Min} and Martin Cl{\'e}mancey and Pascale Maldivi and Latour, {Jean Marc} and Ritimukta Sarangi and Shunichi Fukuzumi and Wonwoo Nam",
note = "Funding Information: This work was supported by the NRF of Korea through CRI (NRF-2012R1A3A2048842). P.M. thanks GENCI for HPC resources (Grant A0040807648). J.-M.L. and P.M. thank the French National Agency for Research (ANR; ARCANE project no. ANR-11-LABX-003). The SSRL SMB resource was supported by an NIH P41 Resource grant (P41GM103393) and by the DOE Office of Biological and Environmental Research. Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",
year = "2019",
month = jan,
day = "9",
doi = "10.1021/jacs.8b11045",
language = "English",
volume = "141",
pages = "80--83",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "1",
}