A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

Woon Young Tcho, Bin Wang, Yong Min Lee, Kyung Bin Cho, Jason Shearer, Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

A mononuclear nonheme cobalt(iii)-hydroperoxide complex bearing a tetramethylated cyclam ligand, [(12-TMC)CoIII(OOH)]2+, was synthesized and characterized spectroscopically and computationally; the cobalt(iii)-hydroperoxide complex exhibited an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions.

Original languageEnglish
Pages (from-to)14511-14515
Number of pages5
JournalDalton Transactions
Volume45
Issue number37
DOIs
StatePublished - 2016

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