A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

Woon Young Tcho; Bin Wang; Yong Min Lee; Kyung Bin Cho; Jason Shearer; Wonwoo Nam

doi:10.1039/c6dt01194b

A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

Woon Young Tcho, Bin Wang, Yong Min Lee, Kyung Bin Cho, Jason Shearer, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

A mononuclear nonheme cobalt(iii)-hydroperoxide complex bearing a tetramethylated cyclam ligand, [(12-TMC)Co^III(OOH)]²⁺, was synthesized and characterized spectroscopically and computationally; the cobalt(iii)-hydroperoxide complex exhibited an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions.

Original language	English
Pages (from-to)	14511-14515
Number of pages	5
Journal	Dalton Transactions
Volume	45
Issue number	37
DOIs	https://doi.org/10.1039/c6dt01194b
State	Published - 2016

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© The Royal Society of Chemistry 2016.

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title = "A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions",

abstract = "A mononuclear nonheme cobalt(iii)-hydroperoxide complex bearing a tetramethylated cyclam ligand, [(12-TMC)CoIII(OOH)]2+, was synthesized and characterized spectroscopically and computationally; the cobalt(iii)-hydroperoxide complex exhibited an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions.",

author = "Tcho, {Woon Young} and Bin Wang and Lee, {Yong Min} and Cho, {Kyung Bin} and Jason Shearer and Wonwoo Nam",

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T1 - A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

AU - Tcho, Woon Young

AU - Wang, Bin

AU - Lee, Yong Min

AU - Cho, Kyung Bin

AU - Shearer, Jason

AU - Nam, Wonwoo

PY - 2016

Y1 - 2016

N2 - A mononuclear nonheme cobalt(iii)-hydroperoxide complex bearing a tetramethylated cyclam ligand, [(12-TMC)CoIII(OOH)]2+, was synthesized and characterized spectroscopically and computationally; the cobalt(iii)-hydroperoxide complex exhibited an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions.

AB - A mononuclear nonheme cobalt(iii)-hydroperoxide complex bearing a tetramethylated cyclam ligand, [(12-TMC)CoIII(OOH)]2+, was synthesized and characterized spectroscopically and computationally; the cobalt(iii)-hydroperoxide complex exhibited an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions.

UR - http://www.scopus.com/inward/record.url?scp=84988568757&partnerID=8YFLogxK

U2 - 10.1039/c6dt01194b

DO - 10.1039/c6dt01194b

M3 - Article

AN - SCOPUS:84988568757

SN - 1477-9226

VL - 45

SP - 14511

EP - 14515

JO - Dalton Transactions

JF - Dalton Transactions

IS - 37

ER -

A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

Abstract

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