A mononuclear manganese(III)-hydroperoxo complex: Synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

Muniyandi Sankaralingam, Yong Min Lee, So Hyun Jeon, Mi Sook Seo, Kyung Bin Cho, Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

29 Scopus citations

Abstract

We report the synthesis of manganese(iii)-peroxo (MnIII(O2)) and manganese(iii)-hydroperoxo (MnIII(O2H)) complexes by activating dioxygen (O2) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.

Original languageEnglish
Pages (from-to)1209-1212
Number of pages4
JournalChemical Communications
Volume54
Issue number10
DOIs
StatePublished - 2018

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