Abstract
We report the synthesis of manganese(iii)-peroxo (MnIII(O2)) and manganese(iii)-hydroperoxo (MnIII(O2H)) complexes by activating dioxygen (O2) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.
Original language | English |
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Pages (from-to) | 1209-1212 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 54 |
Issue number | 10 |
DOIs | |
State | Published - 2018 |
Bibliographical note
Funding Information:This work was supported by the NRF of Korea through CRI (NRF-2012R1A3A2048842), GRL (NRF-2010-00353) (to W. N.), MSIP (NRF-2013R1A1A2062737 to K.-B. C.), and the Basic Science Research Program (2017R1D1A1B03029982 to Y. M. L.).
Publisher Copyright:
© The Royal Society of Chemistry 2018.