We report the synthesis of manganese(iii)-peroxo (MnIII(O2)) and manganese(iii)-hydroperoxo (MnIII(O2H)) complexes by activating dioxygen (O2) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.
Bibliographical noteFunding Information:
This work was supported by the NRF of Korea through CRI (NRF-2012R1A3A2048842), GRL (NRF-2010-00353) (to W. N.), MSIP (NRF-2013R1A1A2062737 to K.-B. C.), and the Basic Science Research Program (2017R1D1A1B03029982 to Y. M. L.).
© The Royal Society of Chemistry 2018.