A mononuclear manganese(III)-hydroperoxo complex: Synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

Muniyandi Sankaralingam; Yong Min Lee; So Hyun Jeon; Mi Sook Seo; Kyung Bin Cho; Wonwoo Nam

doi:10.1039/c7cc09492b

A mononuclear manganese(III)-hydroperoxo complex: Synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

Muniyandi Sankaralingam, Yong Min Lee, So Hyun Jeon, Mi Sook Seo, Kyung Bin Cho, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

We report the synthesis of manganese(iii)-peroxo (Mn^III(O₂)) and manganese(iii)-hydroperoxo (Mn^III(O₂H)) complexes by activating dioxygen (O₂) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.

Original language	English
Pages (from-to)	1209-1212
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	10
DOIs	https://doi.org/10.1039/c7cc09492b
State	Published - 2018

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© The Royal Society of Chemistry 2018.

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title = "A mononuclear manganese(III)-hydroperoxo complex: Synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions",

abstract = "We report the synthesis of manganese(iii)-peroxo (MnIII(O2)) and manganese(iii)-hydroperoxo (MnIII(O2H)) complexes by activating dioxygen (O2) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.",

author = "Muniyandi Sankaralingam and Lee, {Yong Min} and Jeon, {So Hyun} and Seo, {Mi Sook} and Cho, {Kyung Bin} and Wonwoo Nam",

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language = "English",

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T2 - Synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

AU - Sankaralingam, Muniyandi

AU - Lee, Yong Min

AU - Jeon, So Hyun

AU - Seo, Mi Sook

AU - Cho, Kyung Bin

AU - Nam, Wonwoo

PY - 2018

Y1 - 2018

N2 - We report the synthesis of manganese(iii)-peroxo (MnIII(O2)) and manganese(iii)-hydroperoxo (MnIII(O2H)) complexes by activating dioxygen (O2) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.

AB - We report the synthesis of manganese(iii)-peroxo (MnIII(O2)) and manganese(iii)-hydroperoxo (MnIII(O2H)) complexes by activating dioxygen (O2) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.

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DO - 10.1039/c7cc09492b

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AN - SCOPUS:85041604026

SN - 1359-7345

VL - 54

SP - 1209

EP - 1212

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

A mononuclear manganese(III)-hydroperoxo complex: Synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

Abstract

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