A mononuclear manganese(III)-hydroperoxo complex: Synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

Muniyandi Sankaralingam; Yong Min Lee; So Hyun Jeon; Mi Sook Seo; Kyung Bin Cho; Wonwoo Nam

doi:10.1039/c7cc09492b

A mononuclear manganese(III)-hydroperoxo complex: Synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

Muniyandi Sankaralingam, Yong Min Lee, So Hyun Jeon, Mi Sook Seo, Kyung Bin Cho, Wonwoo Nam

Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

We report the synthesis of manganese(iii)-peroxo (Mn^III(O₂)) and manganese(iii)-hydroperoxo (Mn^III(O₂H)) complexes by activating dioxygen (O₂) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.

Original language	English
Pages (from-to)	1209-1212
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	10
DOIs	https://doi.org/10.1039/c7cc09492b
State	Published - 2018

Bibliographical note

Funding Information:
This work was supported by the NRF of Korea through CRI (NRF-2012R1A3A2048842), GRL (NRF-2010-00353) (to W. N.), MSIP (NRF-2013R1A1A2062737 to K.-B. C.), and the Basic Science Research Program (2017R1D1A1B03029982 to Y. M. L.).

Publisher Copyright:
© The Royal Society of Chemistry 2018.

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title = "A mononuclear manganese(III)-hydroperoxo complex: Synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions",

abstract = "We report the synthesis of manganese(iii)-peroxo (MnIII(O2)) and manganese(iii)-hydroperoxo (MnIII(O2H)) complexes by activating dioxygen (O2) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.",

author = "Muniyandi Sankaralingam and Lee, {Yong Min} and Jeon, {So Hyun} and Seo, {Mi Sook} and Cho, {Kyung Bin} and Wonwoo Nam",

note = "Funding Information: This work was supported by the NRF of Korea through CRI (NRF-2012R1A3A2048842), GRL (NRF-2010-00353) (to W. N.), MSIP (NRF-2013R1A1A2062737 to K.-B. C.), and the Basic Science Research Program (2017R1D1A1B03029982 to Y. M. L.). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2018.",

year = "2018",

doi = "10.1039/c7cc09492b",

language = "English",

volume = "54",

pages = "1209--1212",

journal = "Chemical Communications",

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TY - JOUR

T1 - A mononuclear manganese(III)-hydroperoxo complex

T2 - Synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

AU - Sankaralingam, Muniyandi

AU - Lee, Yong Min

AU - Jeon, So Hyun

AU - Seo, Mi Sook

AU - Cho, Kyung Bin

AU - Nam, Wonwoo

N1 - Funding Information: This work was supported by the NRF of Korea through CRI (NRF-2012R1A3A2048842), GRL (NRF-2010-00353) (to W. N.), MSIP (NRF-2013R1A1A2062737 to K.-B. C.), and the Basic Science Research Program (2017R1D1A1B03029982 to Y. M. L.). Publisher Copyright: © The Royal Society of Chemistry 2018.

PY - 2018

Y1 - 2018

N2 - We report the synthesis of manganese(iii)-peroxo (MnIII(O2)) and manganese(iii)-hydroperoxo (MnIII(O2H)) complexes by activating dioxygen (O2) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.

AB - We report the synthesis of manganese(iii)-peroxo (MnIII(O2)) and manganese(iii)-hydroperoxo (MnIII(O2H)) complexes by activating dioxygen (O2) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.

UR - http://www.scopus.com/inward/record.url?scp=85041604026&partnerID=8YFLogxK

U2 - 10.1039/c7cc09492b

DO - 10.1039/c7cc09492b

M3 - Article

C2 - 29335701

AN - SCOPUS:85041604026

SN - 1359-7345

VL - 54

SP - 1209

EP - 1212

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

A mononuclear manganese(III)-hydroperoxo complex: Synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

Abstract

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