A ferric-cyanide-bridged one-dimensional dirhodium complex with (18-crown-6)potassium cations

Youngmee Kim; Sung Jin Kim; Wonwoo Nam

doi:10.1107/S0108270100019776

A ferric-cyanide-bridged one-dimensional dirhodium complex with (18-crown-6)potassium cations

Youngmee Kim
, Sung Jin Kim
, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The crystal structure of the title compound, catena-poly[bis-[aqua(18-crown-6)potassium] diaqua(18-crown-6)potassium [[tetra-μ-benzoato-2:3κ⁸O:O′-μ-cyano- 1:2κ²C:N-tetracyano-1κC-irondirhodium(Rh-Rh)]-μ-cyano- 1κC:3′κN] octahydrate], [K(18-crown-6) (H₂O)]₂[K(18-crown-6)(H₂O)₂] [FeRh₂-(C₇H₅O₂)₄ (CN)₆]·8H₂O, where (18-crown-6) is 1,4,7,10,13,16-hexaoxacyclooctadecane (C₁₂H₂₄O₆), has been determined. Ferric cyanides connect the dirhodium units to form a one-dimensional chain compound. [K(18-crown-6-ether)(H₂O)₂] cations (with inversion symmetry) and [K(18-crown-6-ether)(H₂O)] cations (in general positions) are located between the chains.

Original language	English
Pages (from-to)	266-268
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	57
Issue number	3
DOIs	https://doi.org/10.1107/S0108270100019776
State	Published - Mar 2001

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@article{cdc1ad7408f04d33a755fc9aa3f92af8,

title = "A ferric-cyanide-bridged one-dimensional dirhodium complex with (18-crown-6)potassium cations",

abstract = "The crystal structure of the title compound, catena-poly[bis-[aqua(18-crown-6)potassium] diaqua(18-crown-6)potassium [[tetra-μ-benzoato-2:3κ8O:O′-μ-cyano- 1:2κ2C:N-tetracyano-1κC-irondirhodium(Rh-Rh)]-μ-cyano- 1κC:3′κN] octahydrate], [K(18-crown-6) (H2O)]2[K(18-crown-6)(H2O)2] [FeRh2-(C7H5O2)4 (CN)6]·8H2O, where (18-crown-6) is 1,4,7,10,13,16-hexaoxacyclooctadecane (C12H24O6), has been determined. Ferric cyanides connect the dirhodium units to form a one-dimensional chain compound. [K(18-crown-6-ether)(H2O)2] cations (with inversion symmetry) and [K(18-crown-6-ether)(H2O)] cations (in general positions) are located between the chains.",

author = "Youngmee Kim and Kim, \{Sung Jin\} and Wonwoo Nam",

year = "2001",

month = mar,

doi = "10.1107/S0108270100019776",

language = "English",

volume = "57",

pages = "266--268",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "3",

}

TY - JOUR

T1 - A ferric-cyanide-bridged one-dimensional dirhodium complex with (18-crown-6)potassium cations

AU - Kim, Youngmee

AU - Kim, Sung Jin

AU - Nam, Wonwoo

PY - 2001/3

Y1 - 2001/3

N2 - The crystal structure of the title compound, catena-poly[bis-[aqua(18-crown-6)potassium] diaqua(18-crown-6)potassium [[tetra-μ-benzoato-2:3κ8O:O′-μ-cyano- 1:2κ2C:N-tetracyano-1κC-irondirhodium(Rh-Rh)]-μ-cyano- 1κC:3′κN] octahydrate], [K(18-crown-6) (H2O)]2[K(18-crown-6)(H2O)2] [FeRh2-(C7H5O2)4 (CN)6]·8H2O, where (18-crown-6) is 1,4,7,10,13,16-hexaoxacyclooctadecane (C12H24O6), has been determined. Ferric cyanides connect the dirhodium units to form a one-dimensional chain compound. [K(18-crown-6-ether)(H2O)2] cations (with inversion symmetry) and [K(18-crown-6-ether)(H2O)] cations (in general positions) are located between the chains.

AB - The crystal structure of the title compound, catena-poly[bis-[aqua(18-crown-6)potassium] diaqua(18-crown-6)potassium [[tetra-μ-benzoato-2:3κ8O:O′-μ-cyano- 1:2κ2C:N-tetracyano-1κC-irondirhodium(Rh-Rh)]-μ-cyano- 1κC:3′κN] octahydrate], [K(18-crown-6) (H2O)]2[K(18-crown-6)(H2O)2] [FeRh2-(C7H5O2)4 (CN)6]·8H2O, where (18-crown-6) is 1,4,7,10,13,16-hexaoxacyclooctadecane (C12H24O6), has been determined. Ferric cyanides connect the dirhodium units to form a one-dimensional chain compound. [K(18-crown-6-ether)(H2O)2] cations (with inversion symmetry) and [K(18-crown-6-ether)(H2O)] cations (in general positions) are located between the chains.

UR - https://www.scopus.com/pages/publications/0035271180

U2 - 10.1107/S0108270100019776

DO - 10.1107/S0108270100019776

M3 - Article

C2 - 11250572

AN - SCOPUS:0035271180

SN - 0108-2701

VL - 57

SP - 266

EP - 268

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 3

ER -

A ferric-cyanide-bridged one-dimensional dirhodium complex with (18-crown-6)potassium cations

Abstract

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