A dream combination for catalysis: Highly reactive and recyclable scandium(III) triflate-catalyzed cyanosilylations of carbonyl compounds in an ionic liquid

Boyoung Y. Park; Ka Yeon Ryu; Jung Hwan Park; Sang Gi Lee

doi:10.1039/b900254e

A dream combination for catalysis: Highly reactive and recyclable scandium(III) triflate-catalyzed cyanosilylations of carbonyl compounds in an ionic liquid

Boyoung Y. Park, Ka Yeon Ryu, Jung Hwan Park, Sang Gi Lee

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

The catalytic activity of lanthanide triflates, particularly scandium triflate, increased dramatically in [bmim][SbF₆], allowing the cyanosilylation of a variety of aldehydes and ketones with a turnover frequency up to 48 000 mol h⁻¹ and a total turnover number of 100 000.

Original language	English
Pages (from-to)	946-994
Number of pages	49
Journal	Green Chemistry
Volume	11
Issue number	7
DOIs	https://doi.org/10.1039/b900254e
State	Published - 6 Jul 2009

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title = "A dream combination for catalysis: Highly reactive and recyclable scandium(III) triflate-catalyzed cyanosilylations of carbonyl compounds in an ionic liquid",

abstract = "The catalytic activity of lanthanide triflates, particularly scandium triflate, increased dramatically in [bmim][SbF6], allowing the cyanosilylation of a variety of aldehydes and ketones with a turnover frequency up to 48 000 mol h−1 and a total turnover number of 100 000.",

author = "Park, {Boyoung Y.} and Ryu, {Ka Yeon} and Park, {Jung Hwan} and Lee, {Sang Gi}",

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AU - Park, Boyoung Y.

AU - Ryu, Ka Yeon

AU - Park, Jung Hwan

AU - Lee, Sang Gi

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AB - The catalytic activity of lanthanide triflates, particularly scandium triflate, increased dramatically in [bmim][SbF6], allowing the cyanosilylation of a variety of aldehydes and ketones with a turnover frequency up to 48 000 mol h−1 and a total turnover number of 100 000.

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JO - Green Chemistry

JF - Green Chemistry

IS - 7

ER -

A dream combination for catalysis: Highly reactive and recyclable scandium(III) triflate-catalyzed cyanosilylations of carbonyl compounds in an ionic liquid

Abstract

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