A dream combination for catalysis: Highly reactive and recyclable scandium(III) triflate-catalyzed cyanosilylations of carbonyl compounds in an ionic liquid

Boyoung Y. Park, Ka Yeon Ryu, Jung Hwan Park, Sang Gi Lee

Research output: Contribution to journalArticlepeer-review

55 Scopus citations

Abstract

The catalytic activity of lanthanide triflates, particularly scandium triflate, increased dramatically in [bmim][SbF6], allowing the cyanosilylation of a variety of aldehydes and ketones with a turnover frequency up to 48 000 mol h−1 and a total turnover number of 100 000.

Original languageEnglish
Pages (from-to)946-994
Number of pages49
JournalGreen Chemistry
Volume11
Issue number7
DOIs
StatePublished - 6 Jul 2009

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