A discrete conglomerate of a distorted Mo(v)-porphyrin with a directly coordinated keggin-type polyoxometalate

Atsutoshi Yokoyama; Takahiko Kojima; Kei Ohkubo; Shunichi Fukuzumi

doi:10.1039/b704994c

A discrete conglomerate of a distorted Mo(v)-porphyrin with a directly coordinated keggin-type polyoxometalate

Atsutoshi Yokoyama
, Takahiko Kojima
, Kei Ohkubo
, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

The reaction of a saddle-distorted Mo(v)-dodecaphenylporphyrin complex and a Keggin-type polyoxometalate gives a discrete and nanosized molecule, [{Mo(DPP)(O)}₂(H₂SiW₁₂O₄₀)], which involves direct coordination between the Mo(v) centers and terminal oxo groups of the polyoxometalate and exhibits excellent stability in solution to show reversible multi-redox processes.

Original language	English
Pages (from-to)	3997-3999
Number of pages	3
Journal	Chemical Communications
Issue number	39
DOIs	https://doi.org/10.1039/b704994c
State	Published - 2007

Access to Document

10.1039/b704994c

Cite this

@article{7d9e47fb31c74ed2bdddc74dcd62dfb2,

title = "A discrete conglomerate of a distorted Mo(v)-porphyrin with a directly coordinated keggin-type polyoxometalate",

abstract = "The reaction of a saddle-distorted Mo(v)-dodecaphenylporphyrin complex and a Keggin-type polyoxometalate gives a discrete and nanosized molecule, [\{Mo(DPP)(O)\}2(H2SiW12O40)], which involves direct coordination between the Mo(v) centers and terminal oxo groups of the polyoxometalate and exhibits excellent stability in solution to show reversible multi-redox processes.",

author = "Atsutoshi Yokoyama and Takahiko Kojima and Kei Ohkubo and Shunichi Fukuzumi",

year = "2007",

doi = "10.1039/b704994c",

language = "English",

pages = "3997--3999",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "39",

}

TY - JOUR

T1 - A discrete conglomerate of a distorted Mo(v)-porphyrin with a directly coordinated keggin-type polyoxometalate

AU - Yokoyama, Atsutoshi

AU - Kojima, Takahiko

AU - Ohkubo, Kei

AU - Fukuzumi, Shunichi

PY - 2007

Y1 - 2007

N2 - The reaction of a saddle-distorted Mo(v)-dodecaphenylporphyrin complex and a Keggin-type polyoxometalate gives a discrete and nanosized molecule, [{Mo(DPP)(O)}2(H2SiW12O40)], which involves direct coordination between the Mo(v) centers and terminal oxo groups of the polyoxometalate and exhibits excellent stability in solution to show reversible multi-redox processes.

AB - The reaction of a saddle-distorted Mo(v)-dodecaphenylporphyrin complex and a Keggin-type polyoxometalate gives a discrete and nanosized molecule, [{Mo(DPP)(O)}2(H2SiW12O40)], which involves direct coordination between the Mo(v) centers and terminal oxo groups of the polyoxometalate and exhibits excellent stability in solution to show reversible multi-redox processes.

UR - https://www.scopus.com/pages/publications/34948910131

U2 - 10.1039/b704994c

DO - 10.1039/b704994c

M3 - Article

AN - SCOPUS:34948910131

SN - 1359-7345

SP - 3997

EP - 3999

JO - Chemical Communications

JF - Chemical Communications

IS - 39

ER -

A discrete conglomerate of a distorted Mo(v)-porphyrin with a directly coordinated keggin-type polyoxometalate

Abstract

Access to Document

Fingerprint

Cite this