A discrete conglomerate of a distorted Mo(v)-porphyrin with a directly coordinated keggin-type polyoxometalate

Atsutoshi Yokoyama, Takahiko Kojima, Kei Ohkubo, Shunichi Fukuzumi

Research output: Contribution to journalArticlepeer-review

80 Scopus citations

Abstract

The reaction of a saddle-distorted Mo(v)-dodecaphenylporphyrin complex and a Keggin-type polyoxometalate gives a discrete and nanosized molecule, [{Mo(DPP)(O)}2(H2SiW12O40)], which involves direct coordination between the Mo(v) centers and terminal oxo groups of the polyoxometalate and exhibits excellent stability in solution to show reversible multi-redox processes.

Original languageEnglish
Pages (from-to)3997-3999
Number of pages3
JournalChemical Communications
Issue number39
DOIs
StatePublished - 2007

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