Abstract
"Chemical Equation Presented" OOH, my! The protonation of a side-on high-spin ferric peroxo species yields the corresponding end-on low-spin ferric hydroperoxo intermediate (see picture), which is a precursor of Compound I and has been frequently proposed as a reactive species in heme enzymes. This ferric hydroperoxo complex can be used to study reactivities of similar species in substrate oxygenation and hydroperoxide O-O bond cleavage reactions.
| Original language | English |
|---|---|
| Pages (from-to) | 2099-2101 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 49 |
| Issue number | 12 |
| DOIs | |
| State | Published - 15 Mar 2010 |
Keywords
- Bioinorganic chemistry
- Ferric hydroperoxo complexes
- Heme proteins
- Oxygen activation
- Porphyrinoids
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