A bench-stable Pd catalyst for the hydroarylation of fullerene with boronic acids

Susumu Mori; Masakazu Nambo; Liang Chen Chi; Jean Bouffard; Kenichiro Itami

doi:10.1021/ol801936j

A bench-stable Pd catalyst for the hydroarylation of fullerene with boronic acids

Susumu Mori, Masakazu Nambo, Liang Chen Chi, Jean Bouffard, Kenichiro Itami

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

60 Scopus citations

Abstract

(Chemical Equation Presented) A Pd(II) catalyst for the hydroarylation of fullerene with boronic acids is presented. Treatment of C₆₀ with an arylboronic acid in the presence of a catalytic amount of Pd(2-PyCH=NPh) (OCOC₆F₅)₂ in H₂O/1,2-Cl ₂C₆H₄ at room temperature furnishes the hydroarylation product (Ar-C₆₀-H) in good yield with high selectivity. This complex possesses high catalytic activity paired with bench stability in the solid state.

Original language	English
Pages (from-to)	4609-4612
Number of pages	4
Journal	Organic Letters
Volume	10
Issue number	20
DOIs	https://doi.org/10.1021/ol801936j
State	Published - 2008

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title = "A bench-stable Pd catalyst for the hydroarylation of fullerene with boronic acids",

abstract = "(Chemical Equation Presented) A Pd(II) catalyst for the hydroarylation of fullerene with boronic acids is presented. Treatment of C60 with an arylboronic acid in the presence of a catalytic amount of Pd(2-PyCH=NPh) (OCOC6F5)2 in H2O/1,2-Cl 2C6H4 at room temperature furnishes the hydroarylation product (Ar-C60-H) in good yield with high selectivity. This complex possesses high catalytic activity paired with bench stability in the solid state.",

author = "Susumu Mori and Masakazu Nambo and Chi, {Liang Chen} and Jean Bouffard and Kenichiro Itami",

year = "2008",

doi = "10.1021/ol801936j",

language = "English",

volume = "10",

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journal = "Organic Letters",

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T1 - A bench-stable Pd catalyst for the hydroarylation of fullerene with boronic acids

AU - Mori, Susumu

AU - Nambo, Masakazu

AU - Chi, Liang Chen

AU - Bouffard, Jean

AU - Itami, Kenichiro

PY - 2008

Y1 - 2008

N2 - (Chemical Equation Presented) A Pd(II) catalyst for the hydroarylation of fullerene with boronic acids is presented. Treatment of C60 with an arylboronic acid in the presence of a catalytic amount of Pd(2-PyCH=NPh) (OCOC6F5)2 in H2O/1,2-Cl 2C6H4 at room temperature furnishes the hydroarylation product (Ar-C60-H) in good yield with high selectivity. This complex possesses high catalytic activity paired with bench stability in the solid state.

AB - (Chemical Equation Presented) A Pd(II) catalyst for the hydroarylation of fullerene with boronic acids is presented. Treatment of C60 with an arylboronic acid in the presence of a catalytic amount of Pd(2-PyCH=NPh) (OCOC6F5)2 in H2O/1,2-Cl 2C6H4 at room temperature furnishes the hydroarylation product (Ar-C60-H) in good yield with high selectivity. This complex possesses high catalytic activity paired with bench stability in the solid state.

UR - http://www.scopus.com/inward/record.url?scp=61349159292&partnerID=8YFLogxK

U2 - 10.1021/ol801936j

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VL - 10

SP - 4609

EP - 4612

JO - Organic Letters

JF - Organic Letters

IS - 20

ER -

A bench-stable Pd catalyst for the hydroarylation of fullerene with boronic acids

Abstract

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