A 20-Å-thick interwoven sheet consisting of nanotubes

Ok Sang Jung; Yun Ju Kim; Kwan Mook Kim; Young A. Lee

doi:10.1021/ja026774s

A 20-Å-thick interwoven sheet consisting of nanotubes

Ok Sang Jung, Yun Ju Kim, Kwan Mook Kim, Young A. Lee

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

114 Scopus citations

Abstract

Slow diffusion of AgNO₃ with Me₂Si(4-Py)₂ yields an interwoven 2-nm-thick sheet consisting of the building block [Ag₃(Me₂Si(4-Py)₂)₄](NO₃)₃·H₂O. The interweaving induces unique nanotunnels with a 16 × 18 Å² cross section with a 7 × 8 Å² square pore. The anion NO₃^- of the skeletal sheet can be reversibly exchanged with appropriately sized anions without the collapse of its structural integrity. The compound has a melting point (140 °C) and exists as the first 2D ionic liquid up to 193 °C.

Original language	English
Pages (from-to)	7906-7907
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	124
Issue number	27
DOIs	https://doi.org/10.1021/ja026774s
State	Published - 10 Jul 2002

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title = "A 20-{\AA}-thick interwoven sheet consisting of nanotubes",

abstract = "Slow diffusion of AgNO3 with Me2Si(4-Py)2 yields an interwoven 2-nm-thick sheet consisting of the building block [Ag3(Me2Si(4-Py)2)4](NO3)3·H2O. The interweaving induces unique nanotunnels with a 16 × 18 {\AA}2 cross section with a 7 × 8 {\AA}2 square pore. The anion NO3- of the skeletal sheet can be reversibly exchanged with appropriately sized anions without the collapse of its structural integrity. The compound has a melting point (140 °C) and exists as the first 2D ionic liquid up to 193 °C.",

author = "Jung, {Ok Sang} and Kim, {Yun Ju} and Kim, {Kwan Mook} and Lee, {Young A.}",

year = "2002",

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AU - Jung, Ok Sang

AU - Kim, Yun Ju

AU - Kim, Kwan Mook

AU - Lee, Young A.

PY - 2002/7/10

Y1 - 2002/7/10

N2 - Slow diffusion of AgNO3 with Me2Si(4-Py)2 yields an interwoven 2-nm-thick sheet consisting of the building block [Ag3(Me2Si(4-Py)2)4](NO3)3·H2O. The interweaving induces unique nanotunnels with a 16 × 18 Å2 cross section with a 7 × 8 Å2 square pore. The anion NO3- of the skeletal sheet can be reversibly exchanged with appropriately sized anions without the collapse of its structural integrity. The compound has a melting point (140 °C) and exists as the first 2D ionic liquid up to 193 °C.

AB - Slow diffusion of AgNO3 with Me2Si(4-Py)2 yields an interwoven 2-nm-thick sheet consisting of the building block [Ag3(Me2Si(4-Py)2)4](NO3)3·H2O. The interweaving induces unique nanotunnels with a 16 × 18 Å2 cross section with a 7 × 8 Å2 square pore. The anion NO3- of the skeletal sheet can be reversibly exchanged with appropriately sized anions without the collapse of its structural integrity. The compound has a melting point (140 °C) and exists as the first 2D ionic liquid up to 193 °C.

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 27

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A 20-Å-thick interwoven sheet consisting of nanotubes

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