@article{bbd18de33ec948b1b73bba7c5253ecf3,
title = "3-Hydroxy-2-(trialkylsilyl)phenyl Triflate: A Benzyne Precursor Triggered via 1,3-C-sp2-to-O Silyl Migration",
abstract = "3-Hydroxy-2-(trialkylsilyl)phenyl triflates are presented as new versatile hydroxyaryne precursors. These are base-activated aryne precursors induced via a C-sp2-to-O 1,3-Brook rearrangement. The reaction of various arynophiles and 3-trialkylsiloxybenzyne generated from 3-hydroxy-2-(trialkylsilyl)phenyl triflate efficiently afforded highly regioselective phenol derivatives. Furthermore, through crossover experiments, the intramolecular mechanism of silyl migration was demonstrated.",
author = "Kwon, {Yong Ju} and Jeon, {Young Kyo} and Sim, {Ha Bin} and Oh, {In Young} and Inji Shin and Kim, {Won Suk}",
note = "Funding Information: This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) (NRF-2015R1A1A1A05001334) and the New & Renewable Energy of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant (No. 20163030013900). Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",
year = "2017",
month = nov,
day = "17",
doi = "10.1021/acs.orglett.7b03160",
language = "English",
volume = "19",
pages = "6224--6227",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "22",
}