2D COS and PCMW2D analysis of the magnetic transitions in Raman spectra of BiFeO3

Thi Minh Hien Nguyen; Xuan Nghia Nguyen; Van Minh Nguyen; Xuan Thang To; Duc Cuong Nguyen; Thi Huyen Nguyen; Xiang Bai Chen; In Sang Yang

doi:10.1016/j.vibspec.2022.103383

2D COS and PCMW2D analysis of the magnetic transitions in Raman spectra of BiFeO₃

Thi Minh Hien Nguyen, Xuan Nghia Nguyen, Van Minh Nguyen, Xuan Thang To, Duc Cuong Nguyen, Thi Huyen Nguyen, Xiang Bai Chen, In Sang Yang

Department of Physics

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

BiFeO₃ is one of the most attracting materials because it is the only known room-temperature multiferroic material. It has been studied by Raman spectroscopy extensively. We perform two-dimensional correlation spectroscopy (2D COS) and perturbation-correlation moving window two-dimensional correlation spectroscopy (PCMW2D) analysis on the temperature-dependent Raman spectra of a BiFeO₃ single crystal. The two low temperature spin reorientation transitions around 135 K and 190 K are confirmed through the significant change in phonon peaks from PCMW2D correlation spectra. We also identify the origin of the mode at ~ 1255 cm⁻¹, which has been controversial until now. In our 2D COS analysis, the intensity of this mode has a strong correlation with the intensity of 145 and 176 cm⁻¹ phonons which correspond to the vibration modes of the Bi-O and Fe-O chemical bonds. We propose that the mode at ~ 1255 cm⁻¹ is the two-phonon scattering of the 551 cm⁻¹ mode assisted by the 145 −176 cm⁻¹ phonons.

Original language	English
Article number	103383
Journal	Vibrational Spectroscopy
Volume	120
DOIs	https://doi.org/10.1016/j.vibspec.2022.103383
State	Published - May 2022

Bibliographical note

Funding Information:
This research is funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) under grand number 103.02-2018.39 . I-S. Y. was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education ( 2021R1A6A1A10039823 ).

Publisher Copyright:
© 2022 Elsevier B.V.

Keywords

Multiferroic BiFeO
Raman scattering, two-dimension correlation spectroscopy, perturbation-correlation moving window two-dimensional correlation spectroscopy

Access to Document

10.1016/j.vibspec.2022.103383

Cite this

@article{28d2fb6e1b9f4f9e97b2e8fd253c4c1b,

title = "2D COS and PCMW2D analysis of the magnetic transitions in Raman spectra of BiFeO3",

abstract = "BiFeO3 is one of the most attracting materials because it is the only known room-temperature multiferroic material. It has been studied by Raman spectroscopy extensively. We perform two-dimensional correlation spectroscopy (2D COS) and perturbation-correlation moving window two-dimensional correlation spectroscopy (PCMW2D) analysis on the temperature-dependent Raman spectra of a BiFeO3 single crystal. The two low temperature spin reorientation transitions around 135 K and 190 K are confirmed through the significant change in phonon peaks from PCMW2D correlation spectra. We also identify the origin of the mode at ~ 1255 cm−1, which has been controversial until now. In our 2D COS analysis, the intensity of this mode has a strong correlation with the intensity of 145 and 176 cm−1 phonons which correspond to the vibration modes of the Bi-O and Fe-O chemical bonds. We propose that the mode at ~ 1255 cm−1 is the two-phonon scattering of the 551 cm−1 mode assisted by the 145 −176 cm−1 phonons.",

keywords = "Multiferroic BiFeO, Raman scattering, two-dimension correlation spectroscopy, perturbation-correlation moving window two-dimensional correlation spectroscopy",

author = "Nguyen, {Thi Minh Hien} and Nguyen, {Xuan Nghia} and Nguyen, {Van Minh} and To, {Xuan Thang} and Nguyen, {Duc Cuong} and Nguyen, {Thi Huyen} and Chen, {Xiang Bai} and Yang, {In Sang}",

note = "Funding Information: This research is funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) under grand number 103.02-2018.39 . I-S. Y. was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education ( 2021R1A6A1A10039823 ). Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",

year = "2022",

month = may,

doi = "10.1016/j.vibspec.2022.103383",

language = "English",

volume = "120",

journal = "Vibrational Spectroscopy",

issn = "0924-2031",

publisher = "Elsevier",

}

TY - JOUR

T1 - 2D COS and PCMW2D analysis of the magnetic transitions in Raman spectra of BiFeO3

AU - Nguyen, Thi Minh Hien

AU - Nguyen, Xuan Nghia

AU - Nguyen, Van Minh

AU - To, Xuan Thang

AU - Nguyen, Duc Cuong

AU - Nguyen, Thi Huyen

AU - Chen, Xiang Bai

AU - Yang, In Sang

N1 - Funding Information: This research is funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) under grand number 103.02-2018.39 . I-S. Y. was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education ( 2021R1A6A1A10039823 ). Publisher Copyright: © 2022 Elsevier B.V.

PY - 2022/5

Y1 - 2022/5

N2 - BiFeO3 is one of the most attracting materials because it is the only known room-temperature multiferroic material. It has been studied by Raman spectroscopy extensively. We perform two-dimensional correlation spectroscopy (2D COS) and perturbation-correlation moving window two-dimensional correlation spectroscopy (PCMW2D) analysis on the temperature-dependent Raman spectra of a BiFeO3 single crystal. The two low temperature spin reorientation transitions around 135 K and 190 K are confirmed through the significant change in phonon peaks from PCMW2D correlation spectra. We also identify the origin of the mode at ~ 1255 cm−1, which has been controversial until now. In our 2D COS analysis, the intensity of this mode has a strong correlation with the intensity of 145 and 176 cm−1 phonons which correspond to the vibration modes of the Bi-O and Fe-O chemical bonds. We propose that the mode at ~ 1255 cm−1 is the two-phonon scattering of the 551 cm−1 mode assisted by the 145 −176 cm−1 phonons.

AB - BiFeO3 is one of the most attracting materials because it is the only known room-temperature multiferroic material. It has been studied by Raman spectroscopy extensively. We perform two-dimensional correlation spectroscopy (2D COS) and perturbation-correlation moving window two-dimensional correlation spectroscopy (PCMW2D) analysis on the temperature-dependent Raman spectra of a BiFeO3 single crystal. The two low temperature spin reorientation transitions around 135 K and 190 K are confirmed through the significant change in phonon peaks from PCMW2D correlation spectra. We also identify the origin of the mode at ~ 1255 cm−1, which has been controversial until now. In our 2D COS analysis, the intensity of this mode has a strong correlation with the intensity of 145 and 176 cm−1 phonons which correspond to the vibration modes of the Bi-O and Fe-O chemical bonds. We propose that the mode at ~ 1255 cm−1 is the two-phonon scattering of the 551 cm−1 mode assisted by the 145 −176 cm−1 phonons.

KW - Multiferroic BiFeO

KW - Raman scattering, two-dimension correlation spectroscopy, perturbation-correlation moving window two-dimensional correlation spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=85129949003&partnerID=8YFLogxK

U2 - 10.1016/j.vibspec.2022.103383

DO - 10.1016/j.vibspec.2022.103383

M3 - Article

AN - SCOPUS:85129949003

SN - 0924-2031

VL - 120

JO - Vibrational Spectroscopy

JF - Vibrational Spectroscopy

M1 - 103383

ER -