η5-cyclopentadienyliron(II)-[14]triphyrin(2.1.1) sandwich compounds: Synthesis, characterization, and stable redox interconversion

Zhaoli Xue; Daiki Kuzuhara; Shinya Ikeda; Yuka Sakakibara; Kei Ohkubo; Naoki Aratani; Tetsuo Okujima; Hidemitsu Uno; Shunichi Fukuzumi; Hiroko Yamada

doi:10.1002/anie.201302815

η⁵-cyclopentadienyliron(II)-[14]triphyrin(2.1.1) sandwich compounds: Synthesis, characterization, and stable redox interconversion

Zhaoli Xue
, Daiki Kuzuhara
, Shinya Ikeda
, Yuka Sakakibara
, Kei Ohkubo
, Naoki Aratani
, Tetsuo Okujima
, Hidemitsu Uno
, Shunichi Fukuzumi
, Hiroko Yamada

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

A semiferrocene complex with a [14]triphyrin(2.1.1) (TriP) ligand has been synthesized. The structure and properties are characterized by X-ray crystallographic analysis, UV/Vis spectroscopy, and variable-temperature ¹H NMR spectroscopy. The Fe^II and Fe^III complexes are electrochemically reversible.

Original language	English
Pages (from-to)	7306-7309
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	28
DOIs	https://doi.org/10.1002/anie.201302815
State	Published - 8 Jul 2013

Keywords

ferrocene
metalloporphyrinoids
redox activity
sandwich complexes
triphyrin

Access to Document

10.1002/anie.201302815

Cite this

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title = "η5-cyclopentadienyliron(II)-[14]triphyrin(2.1.1) sandwich compounds: Synthesis, characterization, and stable redox interconversion",

abstract = "A semiferrocene complex with a [14]triphyrin(2.1.1) (TriP) ligand has been synthesized. The structure and properties are characterized by X-ray crystallographic analysis, UV/Vis spectroscopy, and variable-temperature 1H NMR spectroscopy. The FeII and FeIII complexes are electrochemically reversible.",

keywords = "ferrocene, metalloporphyrinoids, redox activity, sandwich complexes, triphyrin",

author = "Zhaoli Xue and Daiki Kuzuhara and Shinya Ikeda and Yuka Sakakibara and Kei Ohkubo and Naoki Aratani and Tetsuo Okujima and Hidemitsu Uno and Shunichi Fukuzumi and Hiroko Yamada",

year = "2013",

month = jul,

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TY - JOUR

T1 - η5-cyclopentadienyliron(II)-[14]triphyrin(2.1.1) sandwich compounds

T2 - Synthesis, characterization, and stable redox interconversion

AU - Xue, Zhaoli

AU - Kuzuhara, Daiki

AU - Ikeda, Shinya

AU - Sakakibara, Yuka

AU - Ohkubo, Kei

AU - Aratani, Naoki

AU - Okujima, Tetsuo

AU - Uno, Hidemitsu

AU - Fukuzumi, Shunichi

AU - Yamada, Hiroko

PY - 2013/7/8

Y1 - 2013/7/8

N2 - A semiferrocene complex with a [14]triphyrin(2.1.1) (TriP) ligand has been synthesized. The structure and properties are characterized by X-ray crystallographic analysis, UV/Vis spectroscopy, and variable-temperature 1H NMR spectroscopy. The FeII and FeIII complexes are electrochemically reversible.

AB - A semiferrocene complex with a [14]triphyrin(2.1.1) (TriP) ligand has been synthesized. The structure and properties are characterized by X-ray crystallographic analysis, UV/Vis spectroscopy, and variable-temperature 1H NMR spectroscopy. The FeII and FeIII complexes are electrochemically reversible.

KW - ferrocene

KW - metalloporphyrinoids

KW - redox activity

KW - sandwich complexes

KW - triphyrin

UR - https://www.scopus.com/pages/publications/84880176812

U2 - 10.1002/anie.201302815

DO - 10.1002/anie.201302815

M3 - Article

C2 - 23720408

AN - SCOPUS:84880176812

SN - 1433-7851

VL - 52

SP - 7306

EP - 7309

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 28