η5-cyclopentadienyliron(II)-[14]triphyrin(2.1.1) sandwich compounds: Synthesis, characterization, and stable redox interconversion

Zhaoli Xue, Daiki Kuzuhara, Shinya Ikeda, Yuka Sakakibara, Kei Ohkubo, Naoki Aratani, Tetsuo Okujima, Hidemitsu Uno, Shunichi Fukuzumi, Hiroko Yamada

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

A semiferrocene complex with a [14]triphyrin(2.1.1) (TriP) ligand has been synthesized. The structure and properties are characterized by X-ray crystallographic analysis, UV/Vis spectroscopy, and variable-temperature 1H NMR spectroscopy. The FeII and FeIII complexes are electrochemically reversible.

Original languageEnglish
Pages (from-to)7306-7309
Number of pages4
JournalAngewandte Chemie - International Edition
Volume52
Issue number28
DOIs
StatePublished - 8 Jul 2013

Keywords

  • ferrocene
  • metalloporphyrinoids
  • redox activity
  • sandwich complexes
  • triphyrin

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